Miami - Dade County |
Code of Ordinances |
Article III. WATER AND SOIL QUALITY |
Division 3. CONTAMINATED SITE CLEANUPS |
§ 24-44. Clean-up Target Levels (CTLs) and Procedures for Site Rehabilitation Actions (SRAs).
(1)
STATE PROGRAM CONTAMINANT CLEAN-UP TARGET LEVELS (CTLs) AND PROCEDURES.
(a)
For contaminants subject to Chapter 62-770, F.A.C., the CTLs and SRA procedures set forth in Chapter 62-777 and 62-770, Florida Administrative Code (F.A.C.) shall apply.
(b)
For sites which have entered into a Brownfields Site Rehabilitation Agreement with the Department or the Florida Department of Environmental Protection pursuant to Chapter 62-785, F.A.C., the CTLs and SRA procedures set forth in Chapter 62-777 and 62-785, F.A.C. shall apply.
(c)
For contaminants subject to Chapter 62-782, F.A.C., the CTLs and SRA procedures set forth in Chapter 62-777 and 62-782, F.A.C. shall apply.
(d)
For lands owned by the state university system, the risk-based clean-up criteria as described in 376.3071, 376.3078, and 376.81, Florida Statutes, shall apply.
(2)
CLEAN-UP TARGET LEVELS (CTLs) AND PROCEDURES FOR SITES OR CONTAMINANTS OTHER THAN THOSE IDENTIFIED IN SECTION 24-44(1).
(a)
Intent. To protect human health, public safety and environmental resources using risk-based corrective action strategies and to establish the point at which a site rehabilitation action is determined to be accomplished.
(b)
The acceptable level of protection for the establishment of human health based CTLs shall be a lifetime excess cancer risk level of one in one million (1.0E-06) and a hazard quotient of one (1) or less. In addition, the CTLs shall be established to protect aquatic life and to prevent nuisance conditions as applicable.
(c)
Applicability. The CTLs set forth in this section are not effluent standards and are not for the purpose of disposal or reuse.
The CTLs and SRA procedures set forth in this section shall not apply to those contaminants that are subject to the Comprehensive Environmental Response, Compensation, and Liability Act of 1980 as amended by the Superfund Amendments and Reauthorization Act of 1986, the Resource Conservation and Recovery Act, the federal Hazardous and Solid Waste Amendments of 1984, or the Toxic Substance Control Act of 1976.
In addition, the soil CTLs set forth in Section 24-44(2)(f)(v)2. shall not apply to contaminants in soil that are present as a result of the application of registered pesticides that were applied in accordance with state and federal law and the EPA approved applicable registered labels. In making a determination of the applicability of CTLs pursuant to this provision, the party or parties responsible for SRAs shall provide records substantiating such pesticide applications to the Department upon request. Notwithstanding the foregoing provisions of Section 24-44(2)(b), if groundwater contains contaminants above the groundwater CTLs set forth in Section 24-44(2)(f)(v)1. as a result of the pesticide application, then the CTLs and SRA procedures set forth in Section 24-44(2) shall apply.
(d)
Party or parties responsible for site rehabilitation actions shall be the discharger or, if the discharger is unknown or the contamination was the result of a previously unreported discharge, the property owner or operator who is subject to the provisions of Section 24-44(2).
(e)
Retroactivity. The CTLs and the SRA procedures set forth herein shall not apply to those contaminants for which, on or before the effective date of this ordinance, a no further action plan, a source removal plan, a remedial action plan or a monitoring only plan has been approved in writing by the Director, or the Director's designee, unless the party or parties responsible for SRAs have failed to comply with the conditions of the plan approval. However, the party or parties responsible for SRAs may elect to complete site rehabilitation as provided in Section 24-44(2).
(f)
The Clean-up Target Levels are as follows:
(i)
The groundwater and surface water CTLs are set forth in Section 24-44(2)(f)(v)1. The groundwater CTLs are equivalent to the numerical standards set forth in Section 24-43.3(2)(h) of this chapter. For contaminants not listed in Section 24-43.3(2)(h), the groundwater CTLs are equivalent to the numerical standards set forth in Chapter 62-550, F.A.C., Table 1, Table 2, Table 3, Table 4, Table 5 and Table 6, as same may be amended from time to time.
For contaminants not listed in Section 24-43.3(2)(h) or Chapter 62-550, F.A.C., Table 1, Table 2, Table 3, Table 4, Table 5 and Table 6, as same may be amended from time to time, groundwater CTLs are based upon the protection of human health and the prevention of nuisance conditions as set forth in Section 24-44(2)(b). The groundwater CTLs have been established using the procedures, equations and input parameters set forth in the DERM Technical Report: "Development of Clean-up Target Levels (CTLs) for Chapter 24 of the Code of Miami-Dade County, Florida" (dated September, 2005).
The surface water CTLs are equivalent to the water quality standards set forth in Section 24-42(4) of this chapter.
For contaminants not listed in Section 24-42(4), the surface water CTLs are based upon the protection of human health and aquatic life and the prevention of nuisance conditions as set forth in Section 24-44(2)(b). The surface water CTLs have been established using the procedures, equations and input parameters set forth in the DERM Technical Report: "Development of Clean-up Target Levels (CTLs) for Chapter 24 of the Code of Miami-Dade County, Florida" (dated September, 2005) and, as applicable, the numerical standards set forth in Chapter 62-302, F.A.C, as same may be amended from time to time.
Notwithstanding the foregoing provisions of Section 24-44(2)(f)(i), no groundwater or surface water CTLs shall be more stringent than the practical quantitation limits or naturally occurring background concentrations determined in a natural background concentration study which has been approved by the Director or the Director's designee.
(ii)
The soil CTLs are set forth in Section 24-44(2)(f)(v)2.. The soil CTLs are based upon the protection of human health as set forth in Section 24-44(2)(b) and groundwater and surface water CTLs set forth in Section 24-44(2)(f)(v)1.. The soil CTLs have been established using the procedures, equations and input parameters set forth in the DERM Technical Report: "Development of Clean-up Target Levels (CTLs) for Chapter 24 of the Code of Miami-Dade County, Florida" (dated September, 2005).
However, the applicable leachability-based soil CTLs may be exceeded if it is demonstrated to the satisfaction of the Director, or the Director's designee, that:
1.
Leachate concentrations do not exceed the applicable groundwater or surface water CTLs set forth in Section 24-44(2)(f)(v)1., using a laboratory leaching procedure which simulates soil leachability and which has been approved by the Director or the Director's designee; or
2.
For soil that is and has been exposed to the elements (i.e., open ground, not covered by impermeable or semi-permeable cover) and subject to infiltration throughout the entire unsaturated zone for a minimum of two years, it has been subsequently demonstrated to the satisfaction of the Director, or the Director's designee, by a minimum of one year of groundwater monitoring data, that contaminants will not leach into the groundwater at concentrations that exceed the applicable groundwater or surface water CTLs set forth in Section 24-44(2)(f)(v)1.. This demonstration shall consider site-specific characteristics such as the thickness of the unsaturated zone, depth and mass of soil contaminants, soil lithology, actual precipitation, concentration gradients, and the chemical and physical characteristics of the contaminants.
Notwithstanding the foregoing provisions of Section 24-44(2)(f)(ii), no soil CTLs shall be more stringent than the practical quantitation limits or naturally occurring background concentrations determined in a natural background concentration study which has been approved by the Director or the Director's designee.
(iii)
The Director, or the Director's designee, may approve alternative CTLs provided that: human health, public safety, and the environment are afforded equivalent protection to that provided in Section 24-44 (2)(f)(i) and Section 24-44(2)(f)(ii); and same are based upon one (1) of the following, or a combination of the following:
1.
The application of the procedures set forth in Section 24-44 (2)(k)(ii) or Section 24-44(2)(1)(ii).
2.
A demonstration, provided in a feasibility study approved by the Director, or the Director's designee, that achieving the CTLs is not feasible utilizing the best available technologies.
3.
Calculations of site-specific soil CTLs using appropriate site-specific soil properties and equations provided in the DERM Technical Report: "Development of Clean-up Target Levels (CTLs) for Chapter 24 of the Code of Miami-Dade County, Florida" (dated September, 2005), and approved by the Director or the Director's designee.
4.
Calculations of site-specific soil CTLs for total recoverable petroleum hydrocarbons (TRPH) based upon the site-specific composition of TRPH, as determined by an analytical method approved by the Director or the Director's designee. Calculations utilized to comply with this provision shall be in accordance with the DERM Technical Report: "Development of Clean-up Target Levels (CTLs) for Chapter 24 of the Code of Miami-Dade County, Florida" (dated September, 2005).
(iv)
The Director, or the Director's designee, shall maintain the DERM Technical Report: "Development of Clean-up Target Levels for Chapter 24 of the Code of Miami-Dade County, Florida" (dated September, 2005) which contains the risk equations, leachability equations and default input parameters used to calculate the CTLs set forth in Section 24-44(2)(f)(v) herein. The aforesaid Technical Report dated September, 2005, a copy of which is attached hereto, is hereby incorporated by reference, as same may be amended from time to time. Any changes, additions or deletions to the aforesaid Technical Report shall be approved by the Board of County Commissioners by ordinance.
(v)
Clean-up Target Levels (CTLs).
1.
Groundwater and Surface Water CTLs.
Table 1 Groundwater and Surface Water Clean-up Target levels
Contaminants CAS# Groundwater Criteria Freshwater Surface Water Criteria Marine Surface Water Criteria Non-Cancer Target Organs/Systems or Effects# Acenaphthene 83-32-9 20 3 3 -Liver Acenaphthylene 208-96-8 210 * * -Liver Acephate 30560-19-1 4 190 190 Cancer - Neurological Acetone 67-64-1 6300 1700 1700 -Kidney -Liver -Neurological Acetonitrile 75-05-8 42 20000 20000 -Mortality Acetophenone 98-86-2 700 7800 7800 -None Specified Acifluorfen, sodium [or Blazer] 62476-59-9 1 190 190 -Kidney Acrolein 107-02-8 3.5 0.4 0.4 -Nasal Acrylamide 79-06-1 0.008 0.3 0.3 Cancer - Neurological Acrylic acid 79-10-7 3500 NA NA -Developmental Acrylonitrile 107-13-1 0.06 0.2 0.2 Cancer -Nasal -Reproductive Alachlor 15972-60-8 2 0.5 0.5 Cancer -Blood Aldicarb [or Temik] 116-06-3 7 0.9 0.9 -Neurological Aldicarb sulfone 1646-88-4 7 46 46 -Neurological Aldicarb sulfoxide 1646-87-3 7 4.2 4.2 -Neurological Aldrin 309-00-2 0.002 0.00014 0.00014 Cancer -Liver Ally [or Metsulfuron, methyl] 74223-64-6 1800 NA NA -Body Weight Allyl alcohol 107-18-6 35 5 5 -Kidney -Liver Allyl chloride 107-05-1 35** NA NA -Neurological Aluminum 7429-90-5 200 13 1500 -Body Weight Aluminum phosphide 20859-73-8 2.8 6.5 6.5 -Body Weight Ametryn 834-12-8 63 6.2 6.2 -Liver Ammonia 7664-41-7 NA 20 NA -Body Weight Ammonia (as Total) 2800 500 500 -Respiratory Ammonium sulfamate 7773-06-0 1400 10000 10000 -Body Weight Anilazine [or Dyrene] 101-05-3 2.8 NA NA -None Specified Aniline 62-53-3 6.1 4 4 Cancer - Blood -Spleen Anthracene 120-12-7 2100 0.3 0.3 -None Specified Antimony 7440-36-0 6 4300 4300 -Blood Aramite 140-57-8 1.4 3 3 -Cancer Aroclor mixture [see PCBs] Arsenic NOCAS 10 50 50 -Cancer -Cardiovascular -Skin Atrazine 1912-24-9 3 1.9 1.9 -Cancer -Cardiovascular Azinphos, methyl [see Guthion] Azobenzene 103-33-3 0.3 3.6 3.6 -Cancer Barium (soluble salts) 7440-39-3 2000 NA NA -Cardiovascular Baygon [or Propoxur] 114-26-1 28 0.4 0.4 -Blood -Neurological Bayleton 43121-43-3 210 500 500 -Blood Benomyl 17804-35-2 35** 0.3 0.3 -Developmental Bensulide 741-58-2 46 NA NA -None Specified Bentazon 25057-89-0 210 NA NA -Blood Benzaldehyde 100-52-7 700 54 54 -Gastrointestinal -Kidney Benzene 71-43-2 1 71.28 71.28 -Cancer -Blood Benzenethiol 108-98-5 0.07 NA NA -Liver Benzidine 92-87-5 0.0002 0.0002 0.0002 -Cancer -Liver -Neurological Benzo(a)anthracene 56-55-3 0.05 * * -Cancer Benzo(a)pyrene 50-32-8 0.2 * * -Cancer Benzo(b)fluoranthene 205-99-2 0.05 * * -Cancer Benzo(g,h,i)perylene 191-24-2 210 * * -Neurological Benzo(k)fluoranthene 207-08-9 0.5 * * -Cancer Benzoic acid 65-85-0 28000 9000 9000 -None Specified Benzotrichloride 98-07-7 0.003 0.002 0.002 -Cancer Benzyl alcohol 100-51-6 2100 500 500 -Gastrointestinal Benzyl chloride 100-44-7 0.2 2 2 -Cancer Beryllium 7440-41-7 4 0.13 0.13 -Cancer -Gastrointestinal -Respiratory Beta radiation NOCAS 4 NA NA -Cancer BHC, alpha- [see Hexachlorocyclohexane, alpha-] (b) BHC, beta- [see Hexachlorocyclohexane, beta-] (b) BHC, delta- [see Hexachlorocyclohexane, delta-] BHC, gamma- [see Hexachlorocyclohexane, gamma-] (b) BHC, gamma- [see Hexachlorocyclohexane, Technical] (b) Bidrin [or Dicrotophos] 141-66-2 0.7 22 22 -Developmental Bioallethrin 28057-48-9 35 NA NA -Liver Biphenyl, 1,1- [or Diphenyl] 92-52-4 0.5 18 18 -Kidney Bis(2-chloro-1-metylethyl)ether [see Bis(2-chloroisopropyl)ether] Bis(2-chloroethyl)ether 111-44-4 0.03 0.5 0.5 -Cancer Bis(2-chloroisopropyl)ether [or Bis(2-chloro-1-metylethyl)ether] 39638-32-9 0.5 23 23 -Cancer -Blood Bis(2-ethylhexyl)adipate 103-23-1 400 33 33 -Cancer -Body Weight Bis(2-ethylhexyl)phthalate [or DEHP] 117-81-7 6 2.2 2.2 -Cancer -Liver Bisphenol A 80-05-7 350 55 55 -Body Weight Blazer [see Acifluorfen, sodium] Boron 7440-42-8 1400 NA NA -Reproductive -Respiratory Bravo [see Chlorothalonil] Bromacil 314-40-9 70** 97 97 -Body Weight Bromate 15541-45-4 10 NA 100000 -Cancer -Kidney Bromochloromethane 74-97-5 91 NA NA -None Specified Bromodichloromethane 75-27-4 0.6 22 22 -Cancer -Kidney Bromoform 75-25-2 4.4 360 360 -Cancer -Liver Bromomethane [or Methyl bromide] 74-83-9 9.8 35 35 -Gastrointestinal -Respiratory Bromoxynil 1689-84-5 140 NA NA -None Specified Bromoxynil octanoate 1689-99-2 140 NA NA -Neurological Butane 106-97-8 9100 NA NA -Neurological -Respiratory Butanol, n- 71-36-3 700 25000 25000 -Neurological Butanol, tert- [see Butyl alcohol, tert-] Butanone, 2- [see Methyl ethyl ketone] Butyl acetate, n- 123-86-4 43 1000 1000 -None Specified Butyl alcohol, tert- [or Butanol, tert-] 75-65-0 1400 NA NA -Kidney -Neurological Butyl benzyl phthalate 85-68-7 140** 26 26 -Liver Butylate 2008-41-5 350 11 11 -Liver Butylbenzene, n- 104-51-8 280 NA NA -Kidney -Liver -Neurological Butylbenzene, sec 135-98-8 280 240 240 -Kidney -Neurological Butylbenzene, tert 98-06-6 280 NA NA -Kidney -Neurological Butylphthalyl butylglycolate 85-70-1 7000 NA NA -None Specified Cadmium 7440-43-9 5 e (0.7852[InH]-3.49) 9.3 -Cancer -Kidney Calcium cyanide 592-01-8 280 NA NA -Neurological -Thyroid Captafol 2425-06-1 4.1 0.9 0.9 -Cancer -Kidney Captan 133-06-2 10 1.9 1.9 -Cancer -Body Weight Carbaryl [or Sevin] 63-25-2 700 0.06 0.06 -Kidney -Liver Carbazole 86-74-8 1.8 47 47 -Cancer Carbofuran 1563-66-2 40 0.1 0.1 -Neurological -Reproductive Carbon disulfide 75-15-0 700 110 110 -Developmental -Neurological Carbon tetrachloride 56-23-5 3 4.42 4.42 -Cancer -Liver Carbophenothion [or Trithion] 786-19-6 0.9 0.1 0.1 -Neurological Carboxin 5234-68-4 700 60 60 -Body Weight CFC 113 [see Trichloro-1,2,2-trifluoroethane, 1,1,2-] NA NA -Adrenals Chloral hydrate 302-17-0 70** NA NA -Gastrointestinal -Neurological Chloramben 133-90-4 110 NA NA -Liver Chlordane (total) (i) 2 0.00059 0.00059 -Cancer -Liver Chloride 16887-00-6 250000 500000 e -None Specified Chlorine 7782-50-5 4000 10 10 -Respiratory Chlorine cyanide [or Cyanogen chloride] 506-77-4 350 1.4 1.4 -Neurological -Thyroid Chlorite (sodium salt) [or Sodium chlorite] 7758-19-2 1000 29 29 -Developmental -Neurological Chloro-1,3-butadiene [or Chloroprene] 126-99-8 140 NA NA -Hair Loss -Nasal Chloro-3-methylphenol, 4- [see Chloro-m-cresol, p-] Chloroacetic acid 79-11-8 14 2500 2500 -Cardiovascular Chloroaniline, p- 106-47-8 28 2.5 2.5 -Spleen Chlorobenzene 108-90-7 100 17 17 -Liver Chlorobenzilate 510-15-6 0.1 0.02 0.02 -Cancer -Body Weight Chloroethane [see Ethyl chloride] Chloroform 67-66-3 70 470.8 470.8 -Cancer -Liver Chloro-m-cresol, p- [or Chloro-3-methylphenol, 4-] 59-50-7 63 100 100 -Body Weight Chloromethane [see Methyl chloride] Chloronaphthalene, beta- 91-58-7 560 1600 1600 -Liver -Respiratory Chloronitrobenzene, p- 100-00-5 1.9 110 110 -Cancer Chlorophenol, 2- 95-57-8 35 130 130 -Reproductive Chlorophenol, 3- 108-43-0 0.1 170 170 -Reproductive Chlorophenol, 4- 106-48-9 0.1 180 180 -Reproductive Chloropicrin 76-06-2 7.3 NA NA -None Specified Chloroprene [see Chloro-1,3-butadiene] Chlorothalonil [or Bravo] 1897-45-6 3.2 0.8 0.8 -Cancer -Kidney Chlorotoluene, o- 95-49-8 140 390 390 -Body Weight Chlorotoluene, p- 106-43-4 140 NA NA -None Specified Chlorpropham 101-21-3 1400 190 190 -Bone Marrow -Kidney -Liver -Spleen Chlorpyrifos 2921-88-2 21 0.002 0.002 -Neurological Chlorpyrifos, methyl 5598-13-0 70 0.04 0.04 -Reproductive Chlorsulfuron 64902-72-3 350 16 16 -Body Weight Chromium (hexavalent) 18540-29-9 NA 11 50 -Cancer -Respiratory Chromium (total) NOCAS 100 11 50 -Cancer Chromium (trivalent) 16065-83-1 NA e (0.819[InH]+0.6848) 520 -None Specified Chrysene 218-01-9 4.8 * * -Cancer Cobalt 7440-48-4 140 NA NA -Cardiovascular -Immunological -Neurological -Reproductive Copper 7440-50-8 1000 e (0.8545[InH]-1.702) 2.9 -Gastrointestinal Copper cyanide 544-92-3 35 -Kidney Coumaphos 56-72-4 1.8 0.004 0.004 -Neurological Cresol, m- [see Methylphenol, 3-] Cresol, o- [see Methylphenol, 2-] Cresol, p- [see Methylphenol, 4-] Crotonaldehyde 123-73-9 0.02 NA NA -Cancer Cumene [or Isopropyl benzene] 98-82-8 0.8 260 260 -Adrenals -Kidney Cyanazine 21725-46-2 0.04 5.5 5.5 -Cancer Cyanide, free 57-12-5 140 5.2 1 -Neurological -Thyroid Cyanogen 460-19-5 280 NA NA -Neurological -Thyroid Cyanogen chloride [see Chlorine cyanide] Cycloate 1134-23-2 35 130 130 -Neurological Cyclohexanone 108-94-1 35000 26000 26000 Cyclohexylamine 108-91-8 1400 4000 4000 -Reproductive Cyhalothrin [or Karate] 68085-85-8 35 18 18 -Developmental Cymene, p- (or 4-Isopropyltoluene) 99-87-6 700 NA NA -Gastrointestinal -Neurological -Skin Cypermethrin 52315-07-8 7** 0.0005 0.0005 -Gastrointestinal Dacthal [or DCPA] 1861-32-1 70 310 310 -Eye -Kidney -Liver -Respiratory -Thyroid Dalapon 75-99-0 200 5000 5000 -Kidney DB, 2,4- [see Dichlorophenoxybutyric acid, 2,4-] DBCP, 1,2- [see Dibromo-3-chloropropane, 1,2-] DDD, 4,4'- [see Dichlorodiphenyl dichloroethane, p,p'] DDE, 4,4'- [see Dichlorodiphenyl dichloroethylene, p,p'-] DDT, 4,4'- [see Dichlorodiphenyl trichloroethane, p,p'-] Decabromodiphenyl ether 1163-19-5 7** NA NA -None Specified DEET 134-62-3 6300 NA NA -Body Weight DEHP [see Bis(2-ethylhexyl)phthalate] Demeton 8065-48-3 0.3 0.1 0.1 -Eye -Neurological Diallate 2303-16-4 0.6 NA NA -Cancer -None Specified Diazinon 333-41-5 6.3 0.002 0.002 -Neurological Dibenz(a,h)anthracene 53-70-3 0.005 * * -Cancer Dibenzofuran 132-64-9 28 67 67 -None Specified Dibromo-3-chloropropane, 1,2- [or DBCP, 1,2-] 96-12-8 0.2 NA NA -Cancer -Reproductive Dibromobenzene, 1,4- 106-37-6 70 240 240 -Liver Dibromochloromethane 124-48-1 0.4 34 34 -Cancer -Liver Dibromoethane, 1,2- [or EDB] 106-93-4 0.02 13 13 -Cancer -Reproductive Dibutyl phthalate 84-74-2 700 23 23 -Mortality Dicamba 1918-00-9 210 200 200 -Developmental Dichloroacetic acid 79-43-6 0.7 1200 1200 -Cancer -Liver -Neurological -Reproductive Dichloroacetonitrile 3018-12-0 5.6** NA NA -None Specified Dichlorobenzene, 1,2- 95-50-1 600 99 99 -Body Weight Dichlorobenzene, 1,3- 541-73-1 210 85 85 -None Specified Dichlorobenzene, 1,4- 106-46-7 75 3 3 -Cancer -Liver Dichlorobenzidine, 3,3'- 91-94-1 0.08 0.03 0.03 -Cancer Dichlorobenzophenone, 4,4'- 90-98-2 210 1600 1600 -None Specified Dichlorodifluoromethane 75-71-8 1400 NA NA -Liver Dichlorodiphenyldichloroethane, p,p'- [or DDD, 4,4'-] 72-54-8 0.1 0.0003 0.0003 -Cancer Dichlorodiphenyldichloroethylene, p,p'- [or DDE, 4,4'-] 72-55-9 0.1 0.0002 0.0002 -Cancer Dichlorodiphenyltrichloroethane, p,p'- [or DDT, 4,4'-] 50-29-3 0.1 0.00059 0.00059 -Cancer -Liver Dichloroethane, 1,1- 75-34-3 70** NA NA -Kidney Dichloroethane, 1,2- [or EDC] 107-06-2 3 37 37 -Cancer -None Specified Dichloroethene, 1,1- 75-35-4 7** 3.2 3.2 -Liver Dichloroethene, 1,2- (mixture) 540-59-0 NA 7000 7000 -Blood -Liver Dichloroethene, cis-1,2- 156-59-2 70 NA NA -Blood Dichloroethene, trans-1,2- 156-60-5 100 11000 11000 -Blood -Liver Dichlorophenol, 2,3- 576-24-9 0.04 56 56 -Immunological Dichlorophenol, 2,4- 120-83-2 0.3 13 13 -Immunological Dichlorophenol, 2,5- 583-78-8 0.5 90 90 -Immunological Dichlorophenol, 2,6- 87-65-0 0.2 73 73 -Immunological Dichlorophenol, 3,4- 95-77-2 0.3 61 61 -Immunological Dichlorophenoxy acetic acid, 2,4- 94-75-7 70 80 80 -Blood -Kidney -Liver Dichlorophenoxy butyric acid, 2,4- [or DB, 2,4-] 94-82-6 56 NA NA -Blood -Cardiovascular Dichloropropane, 1,2- 78-87-5 5 14 14 -Cancer -Nasal Dichloropropene, 1,3- 542-75-6 0.4 12 12 -Cancer -Gastrointestinal -Nasal Dichlorprop 120-36-5 35 42 42 -None Specified Dichlorvos 62-73-7 0.1 0.005 0.005 -Cancer -Neurological Dicofol [or Kelthane] 115-32-2 0.08 0.006 0.006 -Cancer -Adrenals Dicrotophos [see Bidrin] Dieldrin 60-57-1 0.002 0.00014 0.00014 -Cancer -Liver Diethyl phthalate 84-66-2 5600 380 380 -Body Weight Diethylene glycol, monoethyl ether 111-90-0 14000 170000 170000 -Kidney Diethylstilbestrol 56-53-1 0.000007 -Cancer Diisopropyl methylphosphonate 1445-75-6 560 13000 13000 -None Specified Dimethoate 60-51-5 1.4 0.1 0.1 -Neurological Dimethoxybenzidine, 3,3'- 119-90-4 2.5 NA NA -Cancer Dimethrin 70-38-2 2100 1.1 1.1 -Liver Dimethylaniline, 2,4- 95-68-1 0.05 1700 1700 -Cancer -Blood -Spleen Dimethylaniline, N,N- 121-69-7 14 1700 1700 -Spleen Dimethylbenzidine, 3,3'- 119-93-7 0.004 NA NA -Cancer Dimethylformamide, N,N- 68-12-2 700 50000 50000 -Gastrointestinal -Liver Dimethylphenol, 2,4- 105-67-9 140 160 160 -Blood -Neurological Dimethylphenol, 2,6- 576-26-1 4.2 560 560 -Kidney -Liver -Spleen Dimethylphenol, 3,4- 95-65-8 7 380 380 -Kidney -Liver -Spleen Dimethylphthalate 131-11-3 70000 1400 1400 -Kidney Dinitrobenzene, 1,2- (o) 528-29-0 2.8 30 30 -Spleen Dinitrobenzene, 1,3- (m) 99-65-0 0.7 72 72 -Spleen Dinitrobenzene, 1,4- (p) 100-25-4 2.8 30 30 -Spleen Dinitro-o-cyclohexylphenol 131-89-5 14 NA NA -Eye Dinitrophenol, 2,4- 51-28-5 14 3 3 -Eye Dinitrotoluene, 2,4- 121-14-2 0.05 9.1 9.1 -Cancer -Liver -Neurological Dinitrotoluene, 2,6- 606-20-2 0.05 0.7 0.7 -Cancer -Blood -Kidney -Neurological Di-n-octylphthalate 117-84-0 140 NA NA -Kidney -Liver Dinoseb 88-85-7 7 5.9 5.9 -Developmental Dioxane, 1,4- 123-91-1 3.2 120 120 -Cancer Dioxins, as total 2,3,7,8-TCDD equivalents (c) 1746-01-6 0.00003 0.000000005 0.000000005 -Cancer Diphenamid 957-51-7 210 1600 1600 -Liver Diphenyl [see Biphenyl, 1,1-] Diphenylamine, N,N- 122-39-4 180 NA NA -Kidney -Liver Diphenylhydrazine, 1,2- 122-66-7 0.04 0.2 0.2 -Cancer Diquat 85-00-7 20 1.5 1.5 -Eye Disulfoton 298-04-4 0.3 0.3 0.3 -Neurological Diuron 330-54-1 14 8 8 -Blood Dyrene [see Anilazine] EDB [see Dibromoethane, 1,2-] EDC [see Dichloroethane, 1,2-] Endosulfan (alpha+beta+sulfate) 115-29-7 42 0.056 0.0087 -Cardiovascular -Kidney Endothall 145-73-3 100 110 110 -Gastrointestinal Endrin 72-20-8 2 0.0023 0.0023 -Liver EPEG [see Ethylphthalyl ethylglycolate] Epichlorohydrin 106-89-8 3.5 130 130 -Cancer -Kidney -Nasal EPN [see Ethyl p-nitrophenyl phenylphosphorothioate] EPTC [see Ethyl dipropylthiocarbamate, S-] Ethanol 64-17-5 10000 NA NA -Developmental Ethion 563-12-2 3.5 0.007 0.007 -Neurological Ethoprop 13194-48-4 0.7 0.3 0.3 -Neurological Ethoxyethanol acetate, 2- 111-15-9 2100 2000 2000 -Developmental Ethoxyethanol, 2- 110-80-5 2800 NA NA -Reproductive Ethyl acetate 141-78-6 6300 6300 6300 -Body Weight Ethyl acrylate 140-88-5 0.4 130 130 -Cancer Ethyl chloride [or Chloroethane] 75-00-3 12 NA NA -Cancer -Developmental Ethyl dipropylthiocarbamate, S- [or EPTC] 759-94-4 180 240 240 -Cardiovascular Ethyl ether 60-29-7 750 130000 130000 -Body Weight Ethyl methacrylate 97-63-2 630 NA NA -Kidney Ethyl p-nitrophenyl phenylphosphorothioate [or EPN] 2104-64-5 0.07 0.02 0.02 -Neurological Ethylbenzene 100-41-4 30 610 610 -Developmental -Kidney -Liver Ethylene diamine 107-15-3 140 800 800 -Blood -Cardiovascular Ethylene glycol 107-21-1 14000 16000 16000 -Kidney Ethylene oxide 75-21-8 0.03 4200 4200 -Cancer Ethylene thiourea [or ETU] 96-45-7 0.3 1300 1300 -Cancer -Thyroid Ethylphthalyl ethylglycolate [or EPEG] 84-72-0 21000 NA NA -Kidney Ethyltoluene, o- 622-96-8 210 NA NA -Body Weight -Liver Ethyltoluene, p- 611-14-3 210 NA NA -Body Weight -Liver ETU [see Ethylene thiourea] Famphur 52-85-7 3.5 NA NA -Blood Fenamiphos 22224-92-6 1.8 0.2 0.2 -Neurological Fensulfothion 115-90-2 1.8 0.5 0.5 -Neurological Fenvalerate [see Pydrin] Fluometuron 2164-17-2 91 190 190 -None Specified Fluoranthene 206-44-0 280 0.3 0.3 -Blood -Kidney -Liver Fluorene 86-73-7 280 30 30 -Blood Fluoride 7782-41-4 2000 10000 5000 -Teeth mottling Fluoridone 59756-60-4 560 110 110 -Kidney -Reproductive Fonofos 944-22-9 14 0.1 0.1 -Liver -Neurological Formaldehyde 50-00-0 600 110 110 -Cancer -Gastrointestinal Formic acid 64-18-6 14000 4500 4500 -Body Weight Furan 110-00-9 7 NA NA -Liver Furfural 98-01-1 21 650 650 -Liver -Nasal Glycidaldehyde 765-34-4 2.8 NA NA -Adrenals -Blood -Kidney Glyphosate [or Roundup] 1071-83-6 700 120 120 -Kidney Gross alpha radiation 14127-62-9 15 15 15 -Cancer Guthion [or Methyl azinphos] 86-50-0 11 0.01 0.01 -Neurological Heptachlor 76-44-8 0.4 0.00021 0.00021 -Cancer -Liver Heptachlor epoxide 1024-57-3 0.2 0.00004 0.00004 -Cancer -Liver Hexachloro-1,3-butadiene 87-68-3 0.4 49.7 49.7 -Cancer -Kidney Hexachlorobenzene 118-74-1 1 0.0003 0.0003 -Cancer -Liver Hexachlorocyclohexane, alpha- [or BHC, alpha-] 319-84-6 0.006 0.005 0.005 -Cancer Hexachlorocyclohexane, beta- [BHC, beta-] 319-85-7 0.02 0.046 0.046 -Cancer Hexachlorocyclohexane, delta- [or BHC, delta-] 319-86-8 2.1 NA NA -Kidney -Liver Hexachlorocyclohexane, gamma- [or Lindane or BHC, gamma-] 58-89-9 0.2 0.063 0.063 -Cancer -Kidney -Liver Hexachlorocyclohexane, technical [or BHC, technical] 608-73-1 0.02 0.02 0.02 -Cancer Hexachlorocyclopentadiene 77-47-4 50 3 3 -Gastrointestinal Hexachlorodibenzo-p-dioxin (mixture) 19408-74-3 0.000006 NA NA -Cancer Hexachloroethane 67-72-1 2.5 3.3 3.3 -Cancer -Kidney Hexachlorophene 70-30-4 2.1 1.1 1.1 -Neurological Hexahydro-1,3,5-trinitro-1,3,5-triazine [or RDX] 121-82-4 0.3 180 180 -Cancer -Reproductive Hexane, n- 110-54-3 6 3400 3400 -Neurological Hexanone, 2- [or Methyl butyl ketone] 591-78-6 280 NA NA -None Specified Hexazinone 51235-04-2 230 25000 25000 -Body Weight HMX [see Octahydro-1,3,5,7-tetranitro-tetrazocine] Hydrogen cyanide (as Cyanide) 74-90-8 140 3.5 3.5 -Neurological -Thyroid Hydrogen sulfide 7783-06-4 21 0.1 0.1 -Gastrointestinal -Nasal Hydroquinone 123-31-9 280 4.5 4.5 -Blood Indeno(1,2,3-cd)pyrene 193-39-5 0.05 * * -Cancer Iprodione 36734-19-7 280 150 150 -Blood Iron 7439-89-6 300 1000 300 -Gastrointestinal Isobutyl alcohol 78-83-1 2100 47000 47000 -Neurological Isophorone 78-59-1 37 650 650 -Cancer -None Specified Isopropyl benzene [see Cumene] 4-Isoproyl toluene [see Cymene] Kelthane [see Dicofol] Kepone 143-50-0 0.004 NA NA -Cancer Lead 7439-92-1 15 e (1.273[InH]-4.705) 8.5 -Neurological Limonene 138-86-3 700 -Kidney -Liver Lindane [see Hexachlorocyclohexane, gamma-] Linuron 330-55-2 1.4** 45 45 -Blood Lithium 7439-93-2 140 NA NA -None Specified Malathion 121-75-5 140 0.1 0.1 -Neurological Maleic anhydride 108-31-6 700 NA NA -Kidney Maleic hydrazide 123-33-1 3500 750 750 -Kidney Mancozeb 8018-01-7 210 3.5 3.5 -Thyroid Maneb 12427-38-2 35 5.5 5.5 -Thyroid Manganese 7439-96-5 50 NA NA -Neurological MCPA [see Methyl-4- chlorophenoxy acetic acid, 2-] MCPP [see Propionic acid, 2-(2-methyl-4-chlorophenoxy)] Mercuric chloride (as Mercury) 7487-94-7 0.2** 0.05 0.05 -Immunological -Kidney Mercury 7439-97-6 2 0.012 0.025 -Neurological Mercury, methyl- [see Methylmercury] Merphos 150-50-5 0.2 NA NA -Neurological Merphos oxide 78-48-8 0.2 0.2 0.2 -Neurological Metalaxyl 57837-19-1 420 37 37 -Blood -Liver -Neurological Methacrylonitrile 126-98-7 0.7 NA NA -Liver Methamidophos 10265-92-6 0.4 0.00001 0.00001 -Neurological Methanol 67-56-1 3500 45000 45000 -Developmental -Eye -Neurological Methidathion 950-37-8 0.7** 0.03 0.03 -Liver Methomyl 16752-77-5 180 1 1 -Kidney -Spleen Methoxy-5-nitroaniline, 2- 99-59-2 0.8 NA NA -Cancer Methoxychlor 72-43-5 40 0.03 0.03 -Developmental -Reproductive Methoxyethanol, 2- 109-86-4 7 NA NA -Reproductive Methyl acetate 79-20-9 3000 NA NA -Liver Methyl acrylate 96-33-3 210 NA NA -None Specified Methyl azinphos [see Guthion] Methyl bromide [see Bromomethane] Methyl butyl ketone [see Hexanone, 2-] Methyl chloride [or Chloromethane] 74-87-3 2.7 470.8 470.8 -Cancer -Neurological Methyl chloroform [see Trichloroethane, 1,1,1-] Methyl ethyl ketone [or Butanone, 2-] 78-93-3 4200 120000 120000 -Developmental Methyl isobutyl ketone [or MIBK] 108-10-1 560 23000 23000 -Kidney -Liver Methyl methacrylate 80-62-6 25 6500 6500 -Nasal Methyl parathion [or Parathion, methyl] 298-00-0 1.8 0.01 0.01 -Blood -Neurological Methyl tert-butyl ether [or MTBE] 1634-04-4 20 34000 34000 -Eye -Kidney -Liver Methyl-4-chlorophenoxy acetic acid, 2- [or MCPA] 94-74-6 3.5 72 72 -Kidney -Liver Methyl-5-nitroaniline, 2- 99-55-8 1.1 NA NA -Cancer Methylaniline, 2- 95-53-4 0.1 26 26 -Cancer Methylene bis(2-chloroaniline), 4,4- 101-14-4 0.3 NA NA -Cancer -Liver -Bladder Methylene bromide 74-95-3 70 NA NA -Blood Methylene chloride 75-09-2 5 1580 1580 -Cancer -Liver Methylmercury [or Mercury, methyl] 22967-92-6 0.07** NA NA -Neurological Methylnaphthalene, 1- 90-12-0 28 95 95 -Nasal Methylnaphthalene, 2- 91-57-6 28 30 30 -Nasal Methylphenol, 2- [or Cresol, o-] 95-48-7 35** 250 250 -Neurological Methylphenol, 3- [or Cresol, m-] 108-39-4 35** 450 450 -Neurological Methylphenol, 4- [or Cresol, p-] 106-44-5 3.5** 70 70 -Neurological -Respiratory Metolachlor 51218-45-2 110** 1.1 1.1 -Body Weight Metribuzin 21087-64-9 180 64 64 -Kidney -Liver Metsulfuron, methyl [see Ally] Mevinphos 7786-34-7 1.8 0.05 0.05 -Neurological MIBK [see Methyl isobutyl ketone] Mirex 2385-85-5 1.4 0.001 0.001 -Liver -Thyroid Molinate 2212-67-1 14 17 17 -Reproductive Molybdenum 7439-98-7 35 NA NA -Gout MTBE [see Methyl tert-butyl ether] Naled 300-76-5 14 0.02 0.02 -Neurological Naphthalene 91-20-3 14** 26 26 -Nasal Naphthylamine, 2- 91-59-8 0.0003 NA NA -Cancer Napropamide 15299-99-7 700 210 210 -Body Weight Nickel 7440-02-0 100 e (0.846[InH]+0.0584) 8.3 -Body Weight Nickel subsulfide 12035-72-2 100 e (0.846[InH]+0.0584) 8.3 -Cancer Nitrate 14797-55-8 10000 NA NA -Blood Nitrate+Nitrite NOCAS 10000 NA NA -Blood Nitrite 14797-65-0 1000 NA NA -Blood Nitroaniline, m- 99-09-2 1.7 NA NA -Cancer -Blood Nitroaniline, o- 88-74-4 21 NA NA -Blood Nitroaniline, p- 100-01-6 1.7 1200 1200 -Cancer -Blood Nitrobenzene 98-95-3 3.5 90 90 -Adrenals -Blood -Kidney -Liver Nitrophenol, 4- 100-02-7 56 55 55 -None Specified Nitroso-di-ethylamine, N- 55-18-5 0.0002 0.008 0.008 -Cancer Nitroso-dimethylamine, N 62-75-9 0.0007 3 3 -Cancer Nitroso-di-n-butylamine, N- 924-16-3 0.006 0.04 0.04 -Cancer Nitroso-di-n-propylamine, N- 621-64-7 0.005 0.5 0.5 -Cancer Nitroso-diphenylamine, N- 86-30-6 7.1 6 6 -Cancer Nitroso-N-methylethylamine, N- 10595-95-6 0.002 0.06 0.06 -Cancer Nitrosopyrrolidine, N- 930-55-2 0.02 NA NA -Cancer Nitrotoluene, m- 99-08-1 140 380 380 -Spleen Nitrotoluene, o- 88-72-2 70 550 550 -Spleen Nitrotoluene, p- 99-99-0 70 550 550 -Spleen Nonylphenol 25154-52-3 8.4 5.9 1.4 -Kidney Norflurazon 27314-13-2 280 NA NA -Kidney -Liver -Thyroid Octahydro-1,3,5,7-tetranitro-tetrazocine [or HMX] 2691-41-0 350 1300 1300 -Blood -Liver Octamethylpyrophosphoramide 152-16-9 14 NA NA -Neurological Oil and Grease NOCAS 5000 5000 5000 -None Specified Oryzalin 19044-88-3 35** NA NA -Adrenals -Blood -Kidney -Liver Oxadiazon 19666-30-9 35 44 44 -Liver Oxamyl 23135-22-0 200 8.5 8.5 -Body Weight Paraquat 1910-42-5 3.2** 47 47 -Respiratory Parathion 56-38-2 4.2** 0.04 0.04 -Neurological Parathion, methyl [see Methyl parathion] PCBs [or Aroclor mixture] 1336-36-3 0.5 0.000045 0.000045 -Cancer -Immunological PCE [see Tetrachloroethene] Pebulate 1114-71-2 350 310 310 -Blood Pendimethalin 40487-42-1 280 10 10 -Liver Pentachlorobenzene 608-93-5 5.6 1.7 1.7 -Kidney -Liver Pentachloronitrobenzene 82-68-8 0.1 0.02 0.02 -Cancer -Liver Pentachlorophenol 87-86-5 1 8.2 7.9 -Cancer -Kidney -Liver Perchlorate 7601-90-3 4 NA NA -Thyroid Permethrin 52645-53-1 350 0.001 0.001 -Liver Phenanthrene 85-01-8 210 * * -Kidney Phenmedipham [or Betanal] 13684-63-4 1800 200 200 -None Specified Phenol 108-95-2 10 6.5 6.5 -Developmental Phenylenediamine, m- 108-45-2 42 NA NA -Liver Phenylenediamine, p- 106-50-3 1300 NA NA -Whole Body Phenylphenol, 2- 90-43-7 18 36 36 -Cancer Phorate 298-02-2 1.4 0.005 0.005 -Neurological Phosmet 732-11-6 140 0.1 0.1 -Liver -Neurological Phosphine 7803-51-2 2.1 NA NA -Body Weight Phthalic anhydride 85-44-9 14000 NA NA -Kidney -Nasal -Respiratory Picloram 1918-02-1 500 70 70 -Liver Polychlorinated dibenzo-p-dioxins [see Dioxins] Polycyclic Aromatic Hydrocarbons (PAHs) 0.031 0.031 -Various Endpoints Potassium cyanide 151-50-8 350 5.5 5.5 -Neurological -Thyroid Profluralin 26399-36-0 42 NA NA -None Specified Prometon 1610-18-0 110 600 600 -None Specified Prometryn 7287-19-6 28 21 21 -Bone Marrow -Kidney -Liver Pronamide 23950-58-5 53** NA NA -None Specified Propachlor 1918-16-7 91 12 12 -Liver Propanil 709-98-8 35 20 20 -Spleen Propargite 2312-35-8 140 1.6 1.6 -None Specified Propazine 139-40-2 14** 190 190 -Body Weight Propham 122-42-9 140 500 500 -Neurological Propiconazole 60207-90-1 91 26 26 -Gastrointestinal Propionic acid, 2-(2-methyl-4-chlorophenoxy) [or MCPP] 93-65-2 7 NA NA -Kidney Propoxur [see Baygon] Propylbenzene, n- 103-65-1 280 NA NA -Kidney -Liver -Neurological Propylene glycol 57-55-6 140000 36000 36000 -Blood -Bone Marrow Propylene glycol monomethyl ether 107-98-2 4900 NA NA -Kidney -Liver -Neurological Propylene oxide 75-56-9 0.1 NA NA -Cancer -Nasal -Respiratory Pydrin [or Fenvalerate] 51630-58-1 180 0.0004 0.0004 -Neurological Pyrene 129-00-0 210 0.3 0.3 -Kidney Pyridine 110-86-1 7 1300 1300 -Liver Quinoline 91-22-5 0.01 NA NA -Cancer Radium, 226 and 228 (combined) 7440-14-4 5 5 5 -Cancer RDX [see Hexahydro-1,3,5-trinitro-1,3,5-triazine] Resmethrin 10453-86-8 210 0.003 0.003 -Reproductive Ronnel 299-84-3 350 0.06 0.06 -Liver Rotenone 83-79-4 28 0.1 0.1 -Developmental Roundup [see Glyphosate] Selenious acid (as Selenium) 7783-00-8 35 40 40 -Hair Loss -Neurological -Skin Selenium 7782-49-2 50 5 71 -Hair Loss -Neurological -Skin Sevin [see Carbaryl] Silver 7440-22-4 100 0.07 0.4 -Skin Silvex [see Trichlorophenoxy propionic acid] Simazine 122-34-9 4 7.3 7.3 -Cancer -Blood Sodium 7440-23-5 160000 NA NA -None Specified Sodium chlorite [see Chlorite (sodium salt)] Sodium cyanide (as Cyanide) 143-33-9 280 3.8 3.8 -Neurological Strontium 7440-24-6 4200 -Bone Strychnine 57-24-9 2.1 38 38 -Mortality Styrene 100-42-5 100 460 460 -Blood -Liver -Neurological Sulfate 14808-79-8 250000 NA NA -None Specified TCDD, 2,3,7,8- [see Dioxins, as total 2,3,7,8-TCDD equivalents] TCE [see Trichloroethene] TCMTB [see Thiocyanomethylthio-benzothiazole, 2-] TDS [see Total dissolved solids] Tebuthiuron 34014-18-1 490 310 310 -Body Weight Temephos 3383-96-8 140 0.002 0.002 -None Specified Temik [see Aldicarb] Terbacil 5902-51-2 91 2500 2500 -Liver -Thyroid Terbufos 13071-79-9 0.2 0.01 0.01 -Neurological Terbutryn 886-50-0 7 3.1 3.1 -Blood Tetrachlorobenzene, 1,2,4,5- 95-94-3 2.1 1.6 1.6 -Kidney Tetrachloroethane, 1,1,1,2- 630-20-6 1.3 NA NA -Cancer -Kidney -Liver Tetrachloroethane, 1,1,2,2- 79-34-5 0.2 10.8 10.8 -Cancer -Liver Tetrachloroethene [or PCE] 127-18-4 3 8.85 8.85 -Cancer -Liver Tetrachlorophenol, 2,3,4,6- 58-90-2 210 4.5 4.5 -Liver Tetraethyl dithiopyrophosphate 3689-24-5 3.5 0.01 0.01 -Bone Marrow -Neurological Thallium 7440-28-0 2 6.3 6.3 -Hair Loss -Liver Thallium sulfate (as Thallium) 7446-18-6 0.6 26 26 -Blood -Hair Loss -Liver Thiobencarb 28249-77-6 70 NA NA -Kidney Thiocyanomethylthio-benzothiazole, 2- [or TCMTB] 21564-17-0 2.8** 0.4 0.4 -Gastrointestinal Thiram 137-26-8 35 0.2 0.2 -Neurological Tin 7440-31-5 4200 NA NA -Kidney -Liver Titanium Dioxide 13463-67-7 28000 NA NA Toluene 108-88-3 40 480 480 -Kidney -Liver -Neurological Toluene-2,4-diamine 95-80-7 0.01 NA NA -Cancer Toluidine, p- 106-49-0 0.2 NA NA -Cancer Total dissolved solids [or TDS] C-010 500000 NA NA -None Specified Toxaphene 8001-35-2 3 0.0002 0.0002 -Cancer -Developmental Triallate 2303-17-5 91 65 65 -Liver -Spleen Tributyltin oxide 56-35-9 2.1 0.05 0.05 -Immunological Trichloro-1,2,2-trifluoroethane, 1,1,2- [or CFC 113] 76-13-1 210000 NA NA -Neurological Trichloroacetic acid 76-03-9 9.1 100000 100000 -None Specified Trichlorobenzene, 1,2,3- 87-61-6 70 85 85 -Adrenals Trichlorobenzene, 1,2,4- 120-82-1 70 23 23 -Adrenals Trichlorobenzene, 1,3,5- 108-70-3 40 NA NA -None Specified Trichloroethane, 1,1,1- [or Methyl chloroform] 71-55-6 200 270 270 -None Specified Trichloroethane, 1,1,2- 79-00-5 5 16 16 -Cancer -Liver Trichloroethene [or TCE] 79-01-6 3 80.7 80.7 -Cancer -None Specified Trichlorofluoromethane 75-69-4 2100 NA NA -Cardiovascular -Kidney -Respiratory Trichlorophenol, 2,4,5- 95-95-4 1 23 23 -Kidney -Liver Trichlorophenol, 2,4,6- 88-06-2 3.2 6.5 6.5 -Cancer Trichlorophenoxy acetic acid, 2,4,5- 93-76-5 70 140 140 -Kidney Trichlorophenoxy propionic acid, 2, (2, 4, 5-) [or Silvex] 93-72-1 50 NA NA -Liver Trichloropropane, 1,1,2- 598-77-6 35 NA NA -Cancer -Kidney -Liver -Thyroid Trichloropropane, 1,2,3- 96-18-4 0.02 0.2 0.2 -Cancer -Kidney -Liver Trichloropropene, 1,2,3- 96-19-5 35 NA NA -Eye Trifluralin 1582-09-8 4.5 0.2 0.2 -Cancer -Blood -Liver Trimethyl phosphate 512-56-1 0.9 NA NA -Cancer Trimethylbenzene, 1,2,3- 526-73-8 10 NA NA -None Specified Trimethylbenzene, 1,2,4- 95-63-6 10 220 220 -None Specified Trimethylbenzene, 1,3,5- 108-67-8 10 220 220 -None Specified Trinitrobenzene, 1,3,5- 99-35-4 210 19 19 -Blood -Spleen Trinitrophenylmethylnitramine 479-45-8 70 -Kidney -Liver -Spleen Trinitrotoluene, 2,4,6- 118-96-7 1.2 49 49 -Cancer -Liver Trithion [see Carbophenothion] TRPH NOCAS 5000 5000 5000 -Multiple Endpoints Mixed Contaminants Uranium, soluble salts 7440-61-1 21 NA NA -Kidney Vanadium 7440-62-2 49 NA NA -Hair Loss Vanadium pentoxide (as Vanadium) 1314-62-1 63 13 13 -Hair Loss Vernam 1929-77-7 7 12 12 -Body Weight Vinyl acetate 108-05-4 88 700 700 -Kidney -Nasal Vinyl chloride (d) 75-01-4 1 2.4 2.4 -Cancer -Liver White phosphorus 7723-14-0 0.1 NA 0.1 -Maternal Death - Reproductive Xylenes, total 1330-20-7 20 370 370 -Neurological Zinc 7440-66-6 5000 e (0.8473[InH]+0.884) 86 -Blood Zinc chloride 7646-85-7 2100 1.5 1.5 -Blood Zinc phosphide 1314-84-7 2.1 NA NA -Body Weight Zineb 12122-67-7 350 14 14 -Thyroid CTLs are expressed in units of ug/l (ppb).
# = These default Target Organ(s)/Systems or Effects are those reported to occur at the doses used to derive the referenced dose. Non-default Target Organ(s)/Systems or Effects may be justified through a detailed toxicological analysis of the chemicals present at a specific site.
* = There are no surface water standards for these individual polycyclic aromatic hydrocarbons. Per Chapter 62-302, F.A.C., the surface water criterion for PolycyclicAromatic Hydrocarbons (PAHs) shall apply to the total concentration of Acenaphthylene, Benzo(a)anthracene, Benzo(a)pyrene, Benzo(fluoranthene, Benzo(g,i,h) perylene, Benzo(k)fluoranthene, Chrysene, Dibenzo(a,h,)anthracene, Indenol(1,2,3-cd)pyrene, and Phenanthrene.
** = Groundwater CTLs for Class C carcinogens with no cancer slope factor were developed using the referenced dose divided by a factor of 10, as described in the DERM Technical Report: Development of Cleanup Target Levels (CTLs) for Chapter 24, of the Code of Miami-Dade County (September 2005).
(a) = Freshwater surface water criterion for Ammonia based on un-ionized ammonia only. All other water criteria for ammonia are based on total ammonia.
(b) = The common name BHC is a misnomer for Hexachlorocyclohexane.
(c) = Criteria for Dioxins, as total 2,3,7,8-TCDD equivalents shall be compared to the total dioxin equivalents for chlorinated dioxin and dibenzofuran congeners using the approach set forth in the DERM Technical Report: Development of Cleanup Target Levels (CTLs) for Chapter 24 of the Code of Miami-Dade County (September 2005).
(d) = Surface water values protective of human health for Vinyl chloride calculated assuming continuous lifetime exposure from birth as described in the DERM Technical Report: Development of Cleanup Target Levels (CTLs) for Chapter 24 of the Code of Miami-Dade County (September 2005).
(e) = Not to exceed 10% above ambient, as set forth in Sec. 24-42(4).
(f) = Hardness-dependent as set forth in Chapter 62-302, F.A.C.
(g) = Criteria for these metals are measured as total recoverable metal. However, they may be applied as dissolved metals when, as part of a permit application, a dissolved metals translator has been established according to the procedures set forth in the document, "Guidance for Establishing a Metals Translator", Florida Department of Environmental Protection, December 17, 2001.
(h) = In the absence of concentration data specific for the III and VI valence states of chromium, total chromium concentrations in surface water shall be compared to the criteria for Chromium (hexavalent).
(i) = 12789-03-6 or 57-74-9
NA = Not available.
None Specified = Target organ(s) not available.
Note: Freshwater and marine surface waters, and groundwater at the point of discharge into surface water shall pass acute and chronic toxicity bioassay tests: The user shall consult the standard definitions for acute and chronic toxicity set forth in F.A.C. 62-302.200(1) and F.A.C. 62-302.200(4), respectively.
Table 2 Soil Clean-up Target Levels
Direct Exposure
Leachability Based on
Contaminants CAS# Residential Commercial/
IndustrialGroundwater Fresh Surface
WaterMarine Surface Water Target Organs/Systems or Effects# Acenaphthene 83-32-9 2400 20000 2.1 0.3 0.3 -Liver Acenaphthylene 208-96-8 1800 20000 27 NA NA -Liver Acephate 30560-19-1 120 720 0.02 0.8 0.8 -Cancer -Neurological Acetaldehyde 75-07-0 15 20 NA NA NA -Nasal Acetone 67-64-1 11000 68000 25 6.8 6.8 -Kidney -Liver -Neurological Acetophenone 98-86-2 3900 32000 3.9 44 44 -None Specified Acifluorfen, sodium [or Blazer] 62476-59-9 28 140 0.1 25 25 -Kidney Acrolein 107-02-8 0.05 0.3 0.01 0.002 0.002 -Nasal Acrylamide 79-06-1 0.1 0.4 0.00003 0.001 0.001 -Cancer -Neurological Acrylic acid 79-10-7 48 250 14 NA NA -Developmental Acrylonitrile 107-13-1 0.3 0.6 0.0003 0.001 0.001 Cancer -Nasal -Reproductive Alachlor 15972-60-8 11 44 0.02 0.005 0.005 -Cancer -Blood Aldicarb [or Temik] 116-06-3 68 920 0.03 0.004 0.004 -Neurological Aldrin 309-00-2 0.06 0.3 0.2 0.01 0.01 -Cancer -Liver Ally [or Metsulfuron, methyl] 74223-64-6 19000 300000 12 NA NA -Body Weight Allyl alcohol 107-18-6 140 970 0.1 0.02 0.02 -Kidney -Liver Allyl chloride 107-05-1 0.5 2.7 0.2 NA NA -Neurological Aluminum 7429-90-5 80000 * *** *** *** -Body Weight Aluminum phosphide 20859-73-8 35 880 *** *** *** -Body Weight Ametryn 834-12-8 670 11000 0.8 0.08 0.08 -Liver Ammonia (a) 7664-41-7 NA NA NA *** NA -Respiratory Ammonia (as Total) 7664-41-7 4400 26,400 *** *** *** -Respiratory Aniline 62-53-3 27 150 0.03 0.02 0.02 -Cancer -Blood -Spleen Anthracene 120-12-7 21000 300000 2500 0.4 0.4 -None Specified Antimony (b) 7440-36-0 27 370 5.4 3900 3900 -Blood Aroclor mixture [see PCBs] Arsenic NOCAS 2.1 12 *** *** *** -Cancer -Cardiovascular -Skin Atrazine 1912-24-9 4.3 19 0.06 0.04 0.04 Cancer -Cardiovascular Azinphos, methyl [see Guthion] Azobenzene 103-33-3 7.9 31 0.03 0.4 0.4 -Cancer Barium (soluble salts) (b) 7440-39-3 120** 130000 1600 NA NA -Cardiovascular Baygon [or Propoxur] 114-26-1 280 4100 0.2 0.002 0.002 -Blood -Neurological Bayleton 43121-43-3 2400 46000 4.8 11 11 -Blood Benomyl 17804-35-2 4000 77000 3.1 0.03 0.03 -Developmental Bentazon 25057-89-0 2100 32000 1.2 NA NA -Blood Benzaldehyde 100-52-7 3300 24000 4.8 0.4 0.4 -Gastrointestinal -Kidney Benzene 71-43-2 1.2 1.7 0.007 0.5 0.5 -Cancer -Blood Benzenethiol 108-98-5 0.2 1.3 0.001 NA NA -Liver Benzidine 92-87-5 0.004 0.02 0.00002 0.00002 0.00002 -Cancer -Liver -Neurological Benzo(a)anthracene 56-55-3 ## ## 0.8 NA NA -Cancer Benzo(a)pyrene 50-32-8 0.1 0.7 8 NA NA -Cancer Benzo(b)fluoranthene 205-99-2 ## ## 2.4 NA NA -Cancer Benzo(g,h,i)perylene 191-24-2 2500 52000 32000 NA NA -Neurological Benzo(k)fluoranthene 207-08-9 ## ## 24 NA NA -Cancer Benzoic acid 65-85-0 180000 * 110 36 36 -None Specified Benzotrichloride 98-07-7 0.04 0.09 0.0001 0.00008 0.00008 -Cancer Benzyl alcohol 100-51-6 26000 670000 9.5 2.3 2.3 -Gastrointestinal Benzyl chloride 100-44-7 1 1.6 0.002 0.02 0.02 -Cancer Beryllium (b) 7440-41-7 120 1400 63 2.1 2.1 -Cancer -Gastrointestinal -Respiratory Betanal [see Phenmedipham] BHC, alpha- [see Hexachloro cyclohexane, alpha-] (f) BHC, beta- [see Hexachloro cyclohexane, beta-] (f) BHC, delta- [see Hexachloro cyclohexane, delta-] (f) BHC, gamma- [see Hexachloro cyclohexane, gamma-] (f) Bidrin [or Dicrotophos] 141-66-2 7.4 120 0.005 0.1 0.1 -Developmental Biphenyl, 1,1- [or Diphenyl] 92-52-4 3000 34000 0.2 5.8 5.8 -Kidney Bis(2-chloro-1-metylethyl)ether [see Bis(2-chloroisopropyl)ether] Bis(2-chloroethoxy)methane 111-91-1 250 5700 63 NA NA -Liver Bis(2-chloroethyl)ether 111-44-4 0.3 0.5 0.0001 0.002 0.002 -Cancer Bis(2-chloroisopropyl)ether [or Bis(2-chloro-1-metylethyl)ether] 39638-32-9 6 12 0.009 0.4 0.4 -Cancer -Blood Bis(2-ethylhexyl)adipate 103-23-1 620 1900 780 64 64 -Cancer -Body Weight Bis(2-ethylhexyl)phthalate [or DEHP] 117-81-7 72 390 3600 1300 1300 -Cancer -Liver Bisphenol A 80-05-7 4000 79000 11 1.7 1.7 -Body Weight Blazer [see Acifluorfen, sodium] Boron 7440-42-8 17000 430000 *** NA NA -Reproductive -Respiratory Bravo [see Chlorothalonil] Bromacil 314-40-9 7500 120000 0.5 0.6 0.6 -Body Weight Bromate 15541-45-4 1 2.8 0.04 NA 460 -Cancer -Kidney Bromochloromethane 74-97-5 95 530 0.6 NA NA -None Specified Bromodichloromethane 75-27-4 1.5 2.2 0.004 0.1 0.1 Cancer -Kidney Bromoform 75-25-2 48 93 0.03 2.7 2.7 -Cancer -Liver Bromomethane [or Methyl bromide] 74-83-9 3.1 16 0.05 0.2 0.2 -Gastrointestinal -Respiratory Bromoxynil 1689-84-5 1600 29000 3 NA NA -None Specified Butanol, n- 71-36-3 2900 21000 3 110 110 -Neurological Butanol, tert- [see Butyl alcohol, tert-] Butanone, 2- [see Methyl ethyl ketone] Butyl alcohol, tert- [or Butanol, tert-] 75-65-0 3200 19000 5.7 NA NA -Kidney -Neurological Butyl benzyl phthalate 85-68-7 17000 380000 310 56 56 -Liver Butylate 2008-41-5 3200 40000 5.2 0.2 0.2 -Liver Butylbenzene, n- 104-51-8 410 2400 21 NA NA -Kidney -Liver -Neurological Butylbenzene, sec 135-98-8 360 2000 19 NA NA -Kidney -Neurological Butylbenzene, tert 98-06-6 360 2100 15 NA NA -Kidney -Neurological Butylphthalyl butylglycolate 85-70-1 84000 * 4200 NA NA -None Specified Cadmium (b,c,h) 7440-43-9 82 1700 7.5 (k) 14 Cancer -Kidney Calcium cyanide 592-01-8 3500 88000 *** NA NA -Neurological -Thyroid Captafol 2425-06-1 110 570 0.5 0.1 0.1 -Cancer -Kidney Captan 133-06-2 230 750 0.1 0.03 0.03 -Cancer -Body Weight Carbaryl [or Sevin] 63-25-2 7700 130000 8.7 0.0007 0.0007 -Kidney -Liver Carbazole 86-74-8 49 240 0.2 6.5 6.5 -Cancer Carbofuran 1563-66-2 130 910 0.2 0.0006 0.0006 -Neurological -Reproductive Carbon disulfide 75-15-0 270 1500 5.6 0.8 0.8 -Developmental -Neurological Carbon tetrachloride 56-23-5 0.5 0.7 0.04 0.06 0.06 -Cancer -Liver Carbophenothion [or Trithion] 786-19-6 11 250 13 1.5 1.5 -Neurological Carboxin 5234-68-4 7400 120000 5 0.4 0.4 -Body Weight CFC 113 [see Trichloro-1,2,2-trifluoroethane, 1,1,2-] -Adrenals Chloral hydrate 302-17-0 5700 62000 0.3 NA NA -Gastrointestinal -Neurological Chloramben 133-90-4 960 12000 0.5 NA NA -Liver Chlordane (total) (j) 2.8 14 9.6 0.003 0.003 -Cancer -Liver Chlorine cyanide [or Cyanogen chloride] 506-77-4 3100 37000 71 0.3 0.3 -Neurological -Thyroid Chloro-1, 1-difluoroethane, 1- 75-68-3 16000 84000 NA NA NA -None Specified Chloro-1,3-butadiene [or Chloroprene] 126-99-8 3.5 19 1.5 NA NA -Hair Loss -Nasal Chloro-3-methylphenol, 4- [see Chloro-m-cresol, p-] Chloroacetic acid 79-11-8 130 1700 0.07 13 13 -Cardiovascular Chloroaniline, p- 106-47-8 270 3700 0.2 0.02 0.02 -Spleen Chlorobenzene 108-90-7 120 650 1.3 0.2 0.2 -Liver Chlorobenzilate 510-15-6 3.6 18 0.1 0.01 0.01 -Cancer -Body Weight Chlorobenzoic acid, p- 74-11-3 16000 290000 28 NA NA -None Specified Chlorobenzotrifluoride, 4- 98-56-6 130 710 5.2 NA NA -Kidney Chlorobutane, 1- 109-69-3 780 4200 26 NA NA -Blood -Neurological Chlorodifluoromethane 75-45-6 16000 82000 NA NA NA -Adrenals -Kidney -Pituitary Chloroethane [see Ethyl chloride] Chloroform 67-66-3 0.4 0.6 0.4 2.8 2.8 Cancer -Liver Chloro-m-cresol, p- [or Chloro-3-methylphenol, 4-] 59-50-7 600 8000 0.4 0.6 0.6 -Body Weight Chloromethane [see Methyl chloride] Chloronaphthalene, beta- 91-58-7 5000 61000 260 740 740 -Liver -Respiratory Chloronitrobenzene, o- 88-73-3 22 51 0.02 NA NA Cancer Chloronitrobenzene, p- 100-00-5 31 73 0.03 1.6 1.6 Cancer Chlorophenol, 2- 95-57-8 130 860 0.7 2.5 2.5 -Reproductive Chlorophenol, 3- 108-43-0 370 5900 0.002 3.1 3.1 -Reproductive Chlorophenol, 4- 106-48-9 330 4400 0.0007 1.2 1.2 -Reproductive Chloroprene [see Chloro-1,3-butadiene] Chloropropane, 2- 75-29-6 47 250 NA NA NA -Liver Chlorothalonil [or Bravo] 1897-45-6 88 420 0.2 0.06 0.06 -Cancer -Kidney Chlorotoluene, o- 95-49-8 200 1200 2.8 7.7 7.7 -Body Weight Chlorotoluene, p- 106-43-4 170 990 2.5 NA NA -None Specified Chlorpropham 101-21-3 16000 310000 51 7 7 -Bone Marrow -Kidney -Liver -Spleen Chlorpyrifos 2921-88-2 250 5000 15 0.001 0.001 -Neurological Chromium (hexavalent) (b) 18540-29-9 310 470 NA 4.2 19 -Cancer -Respiratory Chromium (total) (b,g) NOCAS 310 470 38 4.2 19 -Cancer Chromium (trivalent) (b) 16065-83-1 110000 * NA NA * -None Specified Chrysene 218-01-9 ## ## 77 NA NA -Cancer Cobalt 7440-48-4 1700 42000 *** NA NA -Cardiovascular -Immunological -Neurological -Reproductive Copper 7440-50-8 150** 89000 *** (k) *** -Gastrointestinal Coumaphos 56-72-4 21 450 0.3 0.0007 0.0007 -Neurological Cresol, m- [see Methylphenol, 3-] Cresol, o- [see Methylphenol, 2-] Cresol, p- [see Methylphenol, 4-] Crotonaldehyde 123-73-9 0.6 3.3 0.00008 NA NA -Cancer Cumene [or Isopropyl benzene] 98-82-8 220 1200 0.2 56 56 -Adrenals -Kidney Cyanide, free (b) 57-12-5 34** 11000 0.56 0.02 0.004 -Neurological -Thyroid Cyanogen 460-19-5 560 3400 57 NA NA -Neurological -Thyroid Cyanogen chloride [see Chlorine cyanide] Cycloate 1134-23-2 340 4700 0.7 2.5 2.5 -Neurological Cyclohexanone 108-94-1 150000 * 150 110 110 Cyclohexylamine 108-91-8 18000 440000 7.9 22 22 -Reproductive Cyhalothrin [or Karate] 68085-85-8 420 9600 290 150 150 -Developmental Cymene, p- (or Isopropyltoluene) 99-87-6 960 5600 NA NA NA -Gastrointestinal -Neurological -Skin Cypermethrin 52315-07-8 840 19000 30 0.002 0.002 -Gastrointestinal DBCP, 1,2- [see Dibromo-3-chloropropane, 1,2-] DDD, 4,4'- [see Dichlorodiphenyl dichloroethane, p,p'] DDE, 4,4'- [see Dichlorodiphenyl dichloroethylene, p,p'-] DDT, 4,4'- [see Dichlorodiphenyl dichloroethane, p,p'-] Decabromodiphenyl ether 1163-19-5 840 19000 9.3 NA NA -None Specified DEHP [see Bis(2-ethylhexyl)phthalate] Diallate 2303-16-4 16 82 0.6 NA NA -Cancer -None Specified Diazinon 333-41-5 70 1200 0.2 0.00005 0.00005 -Neurological Dibenz(a,h)anthracene 53-70-3 ## ## 0.7 NA NA -Cancer Dibenzofuran 132-64-9 320 6300 15 36 36 -None Specified Dibromo-3-chloropropane, 1,2- [or DBCP, 1,2-] 96-12-8 0.7 3.8 0.001 NA NA -Cancer -Reproductive Dibromobenzene, 1,4- 106-37-6 430 3600 7.8 27 27 -Liver Dibromochloromethane 124-48-1 1.5 2.3 0.003 0.2 0.2 -Cancer -Liver Dibromoethane, 1,2- [or EDB] 106-93-4 0.1 0.2 0.0001 0.07 0.07 -Cancer -Reproductive Dibutyl phthalate 84-74-2 8200 170000 47 1.5 1.5 -Mortality Dicamba 1918-00-9 2300 40000 2.6 2.4 2.4 -Developmental Dichloroacetic acid 79-43-6 21 120 0.005 8.1 8.1 -Cancer -Liver -Neurological -Reproductive Dichloroacetonitrile 3018-12-0 340 2900 0.03 NA NA -None Specified Dichlorobenzene, 1,2- 95-50-1 880 5000 17 2.8 2.8 -Body Weight Dichlorobenzene, 1,3- 541-73-1 380 2200 7 2.8 2.8 -None Specified Dichlorobenzene, 1,4- 106-46-7 6.4 9.9 2.2 0.09 0.09 -Cancer -Liver Dichlorobenzidine, 3,3'- 91-94-1 2.1 9.9 0.003 0.0009 0.0009 Cancer Dichlorobenzophenone, 4,4'- 90-98-2 2500 51000 25 190 190 -None Specified Dichlorodifluoromethane 75-71-8 77 410 44 NA NA -Liver Dichlorodiphenyl-
dichloroethane, p,p'- [or DDD, 4,4'-]72-54-8 4.2 22 5.8 0.01 0.01 Cancer Dichlorodiphenyl-
dichloroethylene, p,p-' [or DDE, 4,4'-]72-55-9 2.9 15 18 0.04 0.04 Cancer Dichlorodiphenyl-
trichloroethane, p,p'- [or DDT, 4,4'-]50-29-3 2.9 15 11 0.06 0.06 -Cancer -Liver Dichloroethane, 1,1- 75-34-3 390 2100 0.4 NA NA -Kidney Dichloroethane, 1,2- [or EDC] 107-06-2 0.5 0.7 0.01 0.2 0.2 -Cancer -None Specified Dichloroethene, 1,1- 75-35-4 95 510 0.06 0.03 0.03 -Liver Dichloroethene, cis-1,2- 156-59-2 33 180 0.4 NA NA -Blood Dichloroethene, trans-1,2- 156-60-5 53 290 0.7 75 75 -Blood -Liver Dichlorophenol, 2,3- 576-24-9 230 4100 0.0008 1.2 1.2 -Immunological Dichlorophenol, 2,4- 120-83-2 190 2400 0.003 0.1 0.1 -Immunological Dichlorophenol, 2,5- 583-78-8 240 4600 0.02 4.3 4.3 -Immunological Dichlorophenol, 2,6- 87-65-0 220 3600 0.007 2.5 2.5 -Immunological Dichlorophenol, 3,4- 95-77-2 230 3700 0.01 2 2 -Immunological Dichlorophenoxy acetic acid, 2,4- 94-75-7 770 13000 0.7 0.9 0.9 -Blood -Kidney -Liver Dichloropropane, 1,2- 78-87-5 0.6 0.9 0.03 0.09 0.09 -Cancer -Nasal Dichloropropene, 1,3- 542-75-6 1.4 2.2 0.002 0.09 0.09 -Cancer -Gastrointestinal -Nasal Dichlorprop 120-36-5 370 5800 0.3 0.3 0.3 -None Specified Dichlorvos 62-73-7 0.3 0.4 0.0006 0.00002 0.00002 -Cancer -Neurological Dicofol [or Kelthane] 115-32-2 2.2 11 0.01 0.0008 0.0008 -Cancer -Adrenals Dicrotophos [see Bidrin] Dieldrin 60-57-1 0.06 0.3 0.002 0.0001 0.0001 -Cancer -Liver Diethyl phthalate 84-66-2 61000 * 86 5.9 5.9 -Body Weight Diethylene glycol, monoethyl ether 111-90-0 130000 * 63 750 750 -Kidney Diisopropyl methylphosphonate 1445-75-6 4500 49000 3.6 85 85 -None Specified Dimethoate 60-51-5 13 170 0.006 0.0004 0.0004 -Neurological Dimethoxybenzidine, 3,3'- 119-90-4 69 330 0.2 NA NA -Cancer Dimethrin 70-38-2 24000 440000 2500 1.3 1.3 -Liver Dimethylaniline, 2,4- 95-68-1 0.5 1 0.0005 19 19 -Cancer -Blood -Spleen Dimethylaniline, N,N- 121-69-7 55 380 0.1 12 12 -Spleen Dimethylbenzidine, 3,3'- 119-93-7 0.1 0.6 0.001 NA NA -Cancer Dimethylformamide, N,N- 68-12-2 1400 8600 3 210 210 -Gastrointestinal -Liver Dimethylphenol, 2,4- 105-67-9 1300 18000 1.7 1.9 1.9 -Blood -Neurological Dimethylphenol, 2,6- 576-26-1 34 370 0.04 5.2 5.2 -Kidney -Liver -Spleen Dimethylphenol, 3,4- 95-65-8 71 1000 0.06 3.4 3.4 -Kidney -Liver -Spleen Dimethylphthalate 131-11-3 690000 * 380 7.8 7.8 -Kidney Dinitrobenzene, 1,2- (o) 528-29-0 23 240 0.01 0.2 0.2 -Spleen Dinitrobenzene, 1,3- (m) 99-65-0 5.8 64 0.004 0.4 0.4 -Spleen Dinitrobenzene, 1,4- (p) 100-25-4 35 890 0.04 0.4 0.4 -Spleen Dinitro-o-cresol, 4,6- 534-52-1 8.4 180 0.4 NA NA -Metabolic Disorders Dinitrophenol, 2,4- 51-28-5 110 1200 0.06 0.01 0.01 -Eye Dinitrotoluene, 2,4- 121-14-2 1.2 4.3 0.0004 0.07 0.07 -Cancer -Liver -Neurological Dinitrotoluene, 2,6- 606-20-2 1.2 3.8 0.0004 0.005 0.005 -Cancer -Blood -Kidney -Neurological Di-n-octylphthalate 117-84-0 1700 39000 480000 NA NA -Kidney -Liver Dinoseb 88-85-7 65 840 0.03 0.03 0.03 -Developmental Dioxane, 1,4- 123-91-1 23 38 0.01 0.5 0.5 -Cancer Dioxins, as total 2,3,7,8-TCDD equivalents (e) 1746-01-6 7E-6 3E-5 0.003 6E-7 6E-7 -Cancer Diphenamid 957-51-7 2300 41000 2.6 20 20 -Liver Diphenyl [see Biphenyl, 1,1-] Diphenylamine, N,N- 122-39-4 2000 40000 14 NA NA -Kidney -Liver Diphenylhydrazine, 1,2- 122-66-7 1.1 4.8 0.002 0.007 0.007 -Cancer Diquat 85-00-7 190 4300 800 60 60 -Eye Disulfoton 298-04-4 3.3 66 0.09 0.1 0.1 -Neurological Diuron 330-54-1 150 2300 0.3 0.2 0.2 -Blood EDB [see Dibromoethane, 1,2-] EDC [see Dichloroethane, 1,2-] Endosulfan (alpha+beta+sulfate) 115-29-7 450 7600 3.8 0.005 0.0008 -Cardiovascular -Kidney Endothall 145-73-3 1800 44000 0.4 0.4 0.4 -Gastrointestinal Endrin 72-20-8 25 510 1 0.001 0.001 -Liver EPEG [see Ethylphthalyl ethylglycolate] Epichlorohydrin 106-89-8 14 80 0.03 1.1 1.1 -Cancer -Kidney -Nasal EPN [see Ethyl p-nitrophenyl phenylphosphorothioate] EPTC [see Ethyl dipropylthiocarbamate, S-] Ethanol 64-17-5 * * 40 NA NA -Developmental Ethion 563-12-2 42 920 1.7 0.003 0.003 -Neurological Ethoprop 13194-48-4 7.4 120 0.005 0.002 0.002 -Neurological Ethoxyethanol acetate, 2- 111-15-9 14000 130000 8.8 8.4 8.4 -Developmental Ethoxyethanol, 2- 110-80-5 10000 72000 13 NA NA -Reproductive Ethyl acetate 141-78-6 9100 53000 26 26 26 -Body Weight Ethyl acrylate 140-88-5 2 3 0.002 0.6 0.6 -Cancer Ethyl chloride [or Chloroethane] 75-00-3 3.9 5.4 0.06 NA NA -Cancer -Developmental Ethyl dipropylthiocarbamate, S- [or EPTC] 759-94-4 1400 14000 11 15 15 -Cardiovascular Ethyl ether 60-29-7 260 1400 5 850 850 -Body Weight Ethyl methacrylate 97-63-2 630 3500 3.5 NA NA -Kidney Ethyl p-nitrophenyl phenylphosphorothioate [or EPN] 2104-64-5 0.8 18 0.02 0.003 0.003 -Neurological Ethylbenzene 100-41-4 1500 9200 0.6 12 12 -Developmental -Kidney -Liver Ethylene diamine 107-15-3 1100 11000 0.6 3.2 3.2 -Blood -Cardiovascular Ethylene glycol 107-21-1 110000 * 56 65 65 -Kidney Ethylene oxide 75-21-8 0.3 0.4 0.0002 20 20 -Cancer Ethylene thiourea [or ETU] 96-45-7 7 57 0.001 5.6 5.6 -Cancer -Thyroid Ethylphthalyl ethylglycolate [or EPEG] 84-72-0 260000 * 1200 NA NA -Kidney Ethyltoluene, o- 622-96-8 320 1900 8.1 NA NA -Body Weight -Liver Ethyltoluene, p- 611-14-3 330 1900 8.1 NA NA -Body Weight -Liver ETU [see Ethylene thiourea] Fenamiphos 22224-92-6 19 340 0.02 0.003 0.003 -Neurological Fensulfothion 115-90-2 19 310 0.01 0.004 0.004 -Neurological Fenvalerate [see Pydrin] Fluometuron 2164-17-2 980 16000 0.9 1.8 1.8 -None Specified Fluoranthene 206-44-0 3200 59000 1200 1.3 1.3 -Blood -Kidney -Liver Fluorene 86-73-7 2600 33000 160 17 17 -Blood Fluoride 7782-41-4 840** 130000 6000 30000 15000 -Teeth mottling Fluoridone 59756-60-4 7000 180000 2500 460 460 -Kidney -Reproductive Fonofos 944-22-9 140 2100 0.4 0.003 0.003 -Liver -Neurological Formaldehyde 50-00-0 23 31 2.4 0.4 0.4 -Cancer -Gastrointestinal Furan 110-00-9 4.8 26 0.09 NA NA -Liver Furfural 98-01-1 190 2400 0.09 2.7 2.7 -Liver -Nasal Glycidaldehyde 765-34-4 15 120 0.01 NA NA -Adrenals -Blood -Kidney Glyphosate [or Roundup] 1071-83-6 8800 220000 3.3 0.5 0.5 -Kidney Guthion [or Methyl azinphos] 86-50-0 120 2400 0.2 0.0002 0.0002 -Neurological Heptachlor 76-44-8 0.2 1 23 0.01 0.01 -Cancer -Liver Heptachlor epoxide 1024-57-3 0.1 0.5 0.6 0.0001 0.0001 -Cancer -Liver Hexachloro-1,3-butadiene 87-68-3 6.2 13 1 110 110 -Cancer -Kidney Hexachlorobenzene 118-74-1 0.4 1.2 2.2 0.0006 0.0006 -Cancer -Liver Hexachlorocyclohexane, alpha- [or BHC, alpha-] 319-84-6 0.1 0.6 0.0003 0.0003 0.0003 -Cancer Hexachlorocyclohexane, beta- [BHC, beta-] 319-85-7 0.5 2.4 0.001 0.003 0.003 -Cancer Hexachlorocyclohexane, delta- [or BHC, delta-] 319-86-8 24 490 0.2 NA NA -Kidney -Liver Hexachlorocyclohexane, gamma- [or Lindane or BHC, gamma-] 58-89-9 0.7 2.5 0.009 0.003 0.003 -Cancer -Kidney -Liver Hexachlorocyclopentadiene 77-47-4 9.5 50 400 24 24 -Gastrointestinal Hexachloroethane 67-72-1 38 87 0.2 0.2 0.2 -Cancer -Kidney Hexachlorophene 70-30-4 26 670 53 26 26 -Neurological Hexahydro-1,3,5-trinitro-1,3,5- triazine [or RDX] 121-82-4 7.7 28 0.002 1.3 1.3 -Cancer -Reproductive Hexane, n- 110-54-3 680 3900 2.1 1200 1200 -Neurological Hexanone, 2- [or Methyl butyl ketone] 591-78-6 24 130 1.4 NA NA -None Specified Hexazinone 51235-04-2 2300 32000 1.1 120 120 -Body Weight Hydroquinone 123-31-9 2600 35000 1.4 0.02 0.02 -Blood Indeno(1,2,3-cd)pyrene 193-39-5 ## ## 6.6 NA NA -Cancer Iron 7439-89-6 53000 * *** *** *** -Gastrointestinal Isobutyl alcohol 78-83-1 6400 42000 8.9 200 200 -Neurological Isophorone 78-59-1 540 1200 0.2 3.8 3.8 -Cancer -None Specified Isopropyl benzene [see Cumene] Isopropyl toluene [see p-Cymene] Karate [see Cyhalothrin, lambda] Kelthane [see Dicofol] Lead (d) 7439-92-1 400 1400 *** (k) *** -Neurological Limonene 138-86-3 640 3600 42 NA NA -Kidney -Liver Lindane [see Hexachlorocyclohexane, gamma-] Linuron 330-55-2 160 3100 0.04 1.4 1.4 -Blood Lithium 7439-93-2 1700 44000 *** NA NA -None Specified Malathion 121-75-5 1500 24000 4.2 0.003 0.003 -Neurological Maleic anhydride 108-31-6 3200 24000 2.8 NA NA -Kidney Maleic hydrazide 123-33-1 1000 5400 16 3.4 3.4 -Kidney Malonitrile 109-77-3 1.2 13 0.0006 NA NA -Liver -Spleen Maneb 12427-38-2 410 8400 2.9 0.5 0.5 -Thyroid Manganese 7439-96-5 3500 43000 *** NA NA -Neurological MCPA [see Methyl-4- chlorophenoxy acetic acid, 2-] MCPP [see Propionic acid, 2-(2-methyl-4-chlorophenoxy)] Mercury (c) 7439-97-6 3 17 2.1 0.01 0.03 -Neurological Mercury, methyl- [see Methylmercury] Merphos 150-50-5 2.5 52 0.5 NA NA -Neurological Merphos oxide 78-48-8 2.5 56 0.3 0.3 0.3 -Neurological Methacrylonitrile 126-98-7 1 5.9 0.003 NA NA -Liver Methamidophos 10265-92-6 3.1 36 0.001 0 0 -Neurological Methanol 67-56-1 13000 90000 14 180 180 -Developmental -Eye -Neurological Methidathion 950-37-8 68 950 0.003 0.0001 0.0001 -Liver Methomyl 16752-77-5 38 200 1.2 0.007 0.007 -Kidney -Spleen Methoxy-5-nitroaniline, 2- 99-59-2 19 71 0.006 NA NA -Cancer Methoxychlor 72-43-5 420 8800 160 0.1 0.1 -Developmental -Reproductive Methyl acetate 79-20-9 6800 38000 16 NA NA -Liver Methyl acrylate 96-33-3 260 1500 0.9 NA NA -None Specified Methyl azinphos [see Guthion] Methyl bromide [see Bromomethane] Methyl butyl ketone [see Hexanone, 2-] Methyl chloride [or Chloromethane] 74-87-3 4 5.7 0.01 2.3 2.3 -Cancer -Neurological Methyl chloroform [see Trichloroethane, 1,1,1-] Methyl ethyl ketone [or Butanone, 2-] 78-93-3 16000 110000 17 490 490 -Developmental Methyl isobutyl ketone [or MIBK] 108-10-1 4300 44000 2.6 110 110 -Kidney -Liver Methyl methacrylate 80-62-6 1900 10000 0.1 32 32 -Nasal Methyl parathion [or Parathion, methyl] 298-00-0 20 370 0.06 0.0003 0.0003 -Blood -Neurological Methyl styrene (mixed) 25013-15-4 120 770 0.8 NA NA -Nasal Methyl styrene, alpha 98-83-9 1500 10000 11 NA NA -Kidney -Liver Methyl tert-butyl ether [or MTBE] 1634-04-4 4400 24000 0.09 150 150 -Eye -Kidney -Liver Methyl-4-chlorophenoxy acetic acid, 2- [or MCPA] 94-74-6 35 500 0.02 0.4 0.4 -Kidney -Liver Methylaniline, 2- 95-53-4 2.6 6.4 0.0009 0.2 0.2 -Cancer Methylene bis(2-chloroaniline), 4,4- 101-14-4 6.4 23 0.001 NA NA -Cancer -Liver -Bladder Methylene bromide 74-95-3 96 550 0.3 NA NA -Blood Methylene chloride 75-09-2 17 26 0.02 7.3 7.3 -Cancer -Liver Methylene diphenyl diisocyanate 101-68-8 400 2100 NA NA NA -Nasal Methylmercury [or Mercury, methyl] 22967-92-6 1.1 6.1 0.002 NA NA -Neurological Methylnaphthalene, 1- 90-12-0 200 1800 3.1 10 10 -Nasal Methylnaphthalene, 2- 91-57-6 210 2100 8.5 9.1 9.1 -Nasal Methylphenol, 2- [or Cresol, o-] 95-48-7 2900 31000 0.3 1.9 1.9 -Neurological Methylphenol, 3- [or Cresol, m-] 108-39-4 2900 33000 0.3 3.3 3.3 -Neurological Methylphenol, 4- [or Cresol, p-] 106-44-5 300 3400 0.03 0.5 0.5 -Neurological -Respiratory Metolachlor 51218-45-2 12000 200000 1.2 0.01 0.01 -Body Weight Metribuzin 21087-64-9 54 290 2.2 0.8 0.8 -Kidney -Liver Metsulfuron, methyl [see Ally] Mevinphos 7786-34-7 18 270 0.01 0.0003 0.0003 -Neurological MIBK [see Methyl isobutyl ketone] Molinate 2212-67-1 120 1300 0.1 0.1 0.1 -Reproductive Molybdenum 7439-98-7 440 11000 *** NA NA -Gout MTBE [see Methyl tert-butyl ether] Naled 300-76-5 150 2400 0.1 0.0002 0.0002 -Neurological Naphthalene 91-20-3 55 300 1.2 2.2 2.2 -Nasal Nickel (b,c) 7440-02-0 340** 35000 130 (k) 11 -Body Weight Nitrate 14797-55-8 140000 * *** NA NA -Blood Nitrite 14797-65-0 8700 220000 *** NA NA -Blood Nitroaniline, m- 99-09-2 21 130 0.01 NA NA -Cancer -Blood Nitroaniline, o- 88-74-4 24 130 0.1 NA NA -Blood Nitroaniline, p- 100-01-6 17 96 0.008 5.9 5.9 -Cancer -Blood Nitrobenzene 98-95-3 18 140 0.02 0.6 0.6 -Adrenals -Blood -Kidney -Liver Nitroglycerin 55-63-0 27 54 0.03 NA NA Cancer -Cardiovascular Nitrophenol, 4- 100-02-7 560 7900 0.3 0.3 0.3 -None Specified Nitroso-di-ethylamine, N- 55-18-5 0.003 0.005 0.000001 0.00003 0.00003 -Cancer Nitroso-dimethylamine, N- 62-75-9 0.009 0.02 0.000003 0.01 0.01 -Cancer Nitroso-di-n-butylamine, N- 924-16-3 0.05 0.08 0.00009 0.0005 0.0005 -Cancer Nitroso-di-n-propylamine, N- 621-64-7 0.08 0.2 0.00005 0.005 0.005 -Cancer Nitroso-diphenylamine, N- 86-30-6 180 730 0.4 0.3 0.3 -Cancer Nitroso-N-methylethylamine, N- 10595-95-6 0.02 0.04 0.000006 0.0002 0.0002 -Cancer Nitrotoluene, m- 99-08-1 640 4700 1.4 3.6 3.6 -Spleen Nitrotoluene, o- 88-72-2 400 3300 0.9 7.3 7.3 -Spleen Nitrotoluene, p- 99-99-0 750 12000 0.9 7.3 7.3 -Spleen Nonylphenol 25154-52-3 100 2200 20 14 3.4 -Kidney Octamethylpyro-
phosphoramide152-16-9 130 1600 0.06 NA NA -Neurological Oxamyl 23135-22-0 1700 22000 0.9 0.04 0.04 -Body Weight Paraquat 1910-42-5 340 5500 16 230 230 -Respiratory Parathion 56-38-2 500 11000 1 0.01 0.01 -Neurological Parathion, methyl [see Methyl parathion] PCBs [or Aroclor mixture] 1336-36-3 0.5 2.6 17 0.002 0.002 -Cancer -Immunological PCE [see Tetrachloroethene] Pebulate 1114-71-2 2000 17000 8.5 7.4 7.4 -Blood Pendimethalin 40487-42-1 3200 58000 28 1 1 -Liver Pentachlorobenzene 608-93-5 45 480 3.9 1.2 1.2 -Kidney -Liver Pentachloronitrobenzene 82-68-8 3.3 12 0.2 0.03 0.03 -Cancer -Liver Pentachlorophenol 87-86-5 7.2 28 0.03 0.2 0.2 -Cancer -Kidney -Liver Permethrin 52645-53-1 4200 96000 2500 0.007 0.007 -Liver Phenanthrene 85-01-8 2200 36000 250 NA NA -Kidney Phenmedipham [or Betanal] 13684-63-4 21000 450000 150 18 18 -None Specified Phenol 108-95-2 500** 220000 0.05 0.03 0.03 -Developmental Phenylenediamine, m- 108-45-2 360 4000 0.2 NA NA -Liver Phenylenediamine, o- 95-54-5 17 54 0.004 NA NA -Cancer Phenylenediamine, p- 106-50-3 12000 160000 6.2 NA NA -Whole Body Phenylphenol, 2- 90-43-7 490 2100 0.4 0.8 0.8 -Cancer Phorate 298-02-2 16 320 0.3 0.001 0.001 -Neurological Phosmet 732-11-6 1600 33000 5 0.004 0.004 -Liver -Neurological Phthalic acid, p- 100-21-0 8000 45000 110 NA NA -Bladder Phthalic anhydride 85-44-9 11000 63000 76 NA NA -Kidney -Nasal -Respiratory Polychlorinated dibenzo-p-dioxins [see Dioxins] Prometon 1610-18-0 1200 23000 2.4 14 14 -None Specified Prometryn 7287-19-6 320 6100 0.7 0.5 0.5 -Bone Marrow -Kidney -Liver Propachlor 1918-16-7 990 17000 1.1 0.1 0.1 -Liver Propanil 709-98-8 390 6700 0.4 0.2 0.2 -Spleen Propazine 139-40-2 1600 28000 0.2 2.7 2.7 -Body Weight Propionic acid, 2-(2-methyl-4-chlorophenoxy) [or MCPP] 93-65-2 64 800 0.03 NA NA -Kidney Propoxur [see Baygon] Propylbenzene, n- 103-65-1 340 1900 12 NA NA Propylene glycol 57-55-6 * * 560 140 140 -Blood -Bone Marrow Propylene glycol monomethyl ether 107-98-2 38000 390000 20 NA NA -Kidney -Liver -Neurological Propylene oxide 75-56-9 3.1 9.3 0.0006 NA NA -Cancer -Nasal -Respiratory Pydrin [or Fenvalerate] 51630-58-1 2100 46000 70 0.0001 0.0001 -Neurological Pyrene 129-00-0 2400 45000 880 1.3 1.3 -Kidney Pyridine 110-86-1 20 130 0.03 5.4 5.4 -Liver Quinoline 91-22-5 0.3 1.3 0.0009 NA NA -Cancer RDX [see Hexahydro-1,3,5-trinitro-1,3,5-triazine] Resmethrin 10453-86-8 2500 56000 1200 0.01 0.01 -Reproductive Ronnel 299-84-3 4200 88000 1300 0.2 0.2 -Liver Roundup [see Glyphosate] Selenium (b,c) 7782-49-2 440 11000 5.2 0.5 7.4 -Hair Loss -Neurological -Skin Sevin [see Carbaryl] Silver (b) 7440-22-4 410 8200 17 0.01 0.06 -Skin Silvex [see Trichlorophenoxy propionic acid] Simazine 122-34-9 7.8 35 0.08 0.1 0.1 -Cancer -Blood Strontium 7440-24-6 52000 * *** NA NA -Bone Strychnine 57-24-9 23 380 0.02 0.3 0.3 -Mortality Styrene 100-42-5 3600 23000 3.6 16 16 -Blood -Liver -Neurological TCDD, 2,3,7,8- [see Dioxins, as total 2,3,7,8-TCDD equivalents] TCE [see Trichloroethene] Temik [see Aldicarb] Terbacil 5902-51-2 920 14000 0.5 14 14 -Liver -Thyroid Terbufos 13071-79-9 1.9 29 0.02 0.001 0.001 -Neurological Terbutryn 886-50-0 88 2200 0.2 0.09 0.09 -Blood Tetrachlorobenzene, 1,2,4,5- 95-94-3 12 100 0.5 0.4 0.4 -Kidney Tetrachloroethane, 1,1,1,2- 630-20-6 2.9 4.3 0.01 NA NA -Cancer -Kidney -Liver Tetrachloroethane, 1,1,2,2- 79-34-5 0.7 1.2 0.001 0.08 0.08 -Cancer -Liver Tetrachloroethene [or PCE] 127-18-4 8.8 18 0.03 0.1 0.1 -Cancer -Liver Tetrachlorophenol, 2,3,4,6- 58-90-2 2100 30000 3.2 0.07 0.07 Liver Tetraethyl dithiopyrophosphate 3689-24-5 35 510 0.1 0.0004 0.0004 -Bone Marrow -Neurological Thallium 7440-28-0 6.1 150 2.8 9 9 -Hair Loss -Liver Thiobencarb 28249-77-6 810 16000 2.9 NA NA -Kidney Thiram 137-26-8 400 7700 1.1 0.005 0.005 -Neurological Tin 7440-31-5 47000 880000 *** NA NA -Kidney -Liver Toluene 108-88-3 7500 60000 0.5 5.6 5.6 -Kidney -Liver -Neurological Toluene diisocyanate, 2,4/2,6-mixture 26471-62-5 1.3 15 NA NA NA -Respiratory Toluidine, p- 106-49-0 2.2 4.5 0.0009 NA NA -Cancer Toxaphene 8001-35-2 0.9 4.5 31 0.002 0.002 -Cancer -Developmental Triallate 2303-17-5 980 16000 8.4 6 6 -Liver -Spleen Tributyltin oxide 56-35-9 25 570 7.6 0.2 0.2 -Immunological Trichloro-1,2,2-trifluoroethane, 1,1,2- [or CFC 113] 76-13-1 18000 96000 11000 NA NA -Neurological Trichloroacetic acid 76-03-9 770 8800 0.04 400 400 -None Specified Trichlorobenzene, 1,2,3- 87-61-6 650 8200 4.6 5.6 5.6 -Adrenals Trichlorobenzene, 1,2,4- 120-82-1 660 8500 5.3 1.7 1.7 -Adrenals Trichlorobenzene, 1,3,5- 108-70-3 260 2300 16 NA NA -None Specified Trichloroethane, 1,1,1- [or Methyl chloroform] 71-55-6 730 3900 1.9 2.6 2.6 -None Specified Trichloroethane, 1,1,2- 79-00-5 1.4 2 0.03 0.09 0.09 -Cancer -Liver Trichloroethene [or TCE] 79-01-6 6.4 9.3 0.03 0.9 0.9 -Cancer -None Specified Trichlorofluoromethane 75-69-4 270 1500 33 NA NA -Cardiovascular -Kidney -Respiratory Trichlorophenol, 2,4,5- 95-95-4 7700 130000 0.07 1.5 1.5 -Kidney -Liver Trichlorophenol, 2,4,6- 88-06-2 70 230 0.06 0.1 0.1 -Cancer Trichlorophenoxy acetic acid, 2,4,5- 93-76-5 690 9500 0.4 0.8 0.8 -Kidney Trichlorophenoxy propionic acid, 2, (2,4,5-) [or Silvex] 93-72-1 660 14000 5.4 NA NA -Liver Trichloropropane, 1,1,2- 598-77-6 76 460 0.3 NA NA -Kidney -Liver -Thyroid Trichloropropane, 1,2,3- 96-18-4 0.06 0.1 0.0001 0.001 0.001 -Cancer -Kidney -Liver Trichloropropene, 1,2,3- 96-19-5 18 98 0.4 NA NA -Eye Triethylamine 121-44-8 41 270 NA NA NA -Nasal Trifluralin 1582-09-8 92 280 3.6 0.2 0.2 -Cancer -Blood -Liver Trimethyl phosphate 512-56-1 19 57 0.004 NA NA -Cancer Trimethylbenzene, 1,2,3- 526-73-8 18 96 0.3 NA NA -None Specified Trimethylbenzene, 1,2,4- 95-63-6 18 95 0.3 7.2 7.2 -None Specified Trimethylbenzene, 1,3,5- 108-67-8 15 80 0.3 6.7 6.7 -None Specified Trinitrobenzene, 1,3,5- 99-35-4 2000 26000 1 0.09 0.09 -Blood -Spleen Trinitrophenyl-
methylnitramine479-45-8 790 15000 1.4 NA NA -Kidney -Liver -Spleen Trinitrotoluene, 2,4,6- 118-96-7 28 97 0.006 0.3 0.3 -Cancer -Liver Trithion [see Carbophenothion] TRPH NOCAS 460 2700 340 340 340 -Multiple Endpoints Mixed Contaminants Uranium, soluble salts 7440-61-1 110 820 *** NA NA -Kidney Vanadium (b) 7440-62-2 67** 10000 980 NA NA -Hair Loss Vernam 1929-77-7 51 510 0.1 0.2 0.2 -Body Weight Vinyl acetate 108-05-4 320 1700 0.4 3 3 -Kidney -Nasal Vinyl chloride (i) 75-01-4 0.2 0.8 0.007 0.02 0.02 -Cancer -Liver Xylenes, total 1330-20-7 130 700 0.2 3.9 3.9 -Neurological Zinc (b,c) 7440-66-6 26000 630000 *** (k) *** -Blood Zinc phosphide 1314-84-7 26 660 *** NA NA -Body Weight Zineb 12122-67-7 4100 82000 19 0.7 0.7 -Thyroid CTLs are expressed in units of mg/kg (ppm) on a dry weight basis and rounded to two significant figures if >1 and to one significant figure if <1.
# = These default Target Organ(s)/Systems or Effects are those reported to occur at the doses used to derive the referenced dose. Non-default Target Organ(s)/Systems or Effects may be justified through a detailed toxicological analysis of the chemicals present at a specific site.
* Contaminant is not a health concern for this exposure scenario.
** Direct exposure value based on acute toxicity considerations. This criterion is applicable in scenarios where children might be exposed to soils (e.g. residences, schools, playgrounds).
*** Leachability values may be derived using the SPLP Test to calculate site-specific SCTLs or may be determined using TCLP in the event oily wastes are present.
## = Site concentrations for carcinogenic polycyclic aromatic hydrocarbons shall be converted to Benzo(a)pyrene equivalents before comparison with the appropriate direct exposure SCTL for Benzo(a)pyrene using the approach described in the DERM Technical Report: Development of Cleanup Target Levels (CTLs) for Chapter 24, of the Code of Miami-Dade County (September 2005).
(a) = See discussion on the development of SCTLs for Ammonia in the DERM Technical Report: Development of Cleanup Target Levels (CTLs) for Chapter 24 of the Code of Miami-Dade County (September 2005).
(b) = Leachability values derived from USEPA Soil Screening Guidance (1996). These values were derived assuming soil pH 6.8. These leachability values are dependent upon both the metal concentration in soil and soil characteristics. Thus, if site-specific soil characteristics are different than the defaults, these leachability values may not apply. If this is the case, site-specific leachability values may be derived using methods such as TCLP or SPLP.
(c) = Phytotoxicity must be considered.
(d) = Residential direct exposure value from USEPA Revised Interim Soil Guidance for CERCLA Sites and RCRA Corrective Action Facilities. OSWER Directive 9355.4-12 (1994). The industrial direct exposure value was derived using methodologies set forth in USEPA "Recommendations of the Technical Review Workgroup for Lead for an Interim Approach to Assessing Risks Associated with Adult Exposures to Lead in Soil', December 1996; and in 'Blood Lead Concentrations of U.S. Adult Females: Summary Statistics from Phases 1 and 2 of the NHANES III', March 2002.
(e) = The SCTL for Dioxins, as total 2,3,7,8-TCDD equivalents should be compared to the total dioxin equivalents for chlorinated dioxin and dibenzofuran congeners using the approach described in the DERM Technical Report: Development of Cleanup Target Levels (CTLs) for Chapter 24 of the Code of Miami-Dade County (September 2005).
(f) = The common name BHC is a misnomer for hexachlorocyclohexane.
(g) = Unless concentratons for both chromium III and VI are known, total chromium concentrations may be compared with direct exposures SCTLs for chromium VI.
(h) = Residential chronic SCTL for cadmium shall be used as a not-to-exceed value because the residential chronic SCTL for cadmium is indistinguishable from the SCTL based on acute toxicity.
(i) = Residential chronic SCTL for vinyl chloride calculated by adding prorated and non-prorated risks, as discussed in the DERM Technical Report: Development of Cleanup Target Levels (CTLs) for Chapter 24 of the Code of Miami-Dade County (September 2005).
(j) = 12789-03-6 or 57-74-9
(k) = Hardness-dependent fresh surface water CTLs shall be calculated using the site-specific hardness prior to calculating the leachcability based upon fresh surface water CTLs or comparing the SPLP leachate concentrations.
None Specified = Target organ(s) not determined.
NA = Not available.
3.
For contaminants not listed in Section 24-44(2)(f)(v), CTLs shall be established as set forth in Section 24-44(2)(f)(i) and Section 24-44(2)(f)(ii). The CTLs calculated pursuant to Section 24-44(2)(f)(v)3. shall be provided in a technical report approved by the Director or the Director's designee.
(g)
All technical plans, reports, proposals, or studies shall be submitted by the party or parties responsible for SRAs in accordance with the written orders of the Director, or the Director's designee, or as set forth herein. The Director, or the Director's designee, shall review each technical plan, report, proposal, or study and approve, approve with modifications or disapprove the aforesaid in writing within sixty (60) calendar days from receipt of the submittal.
To facilitate a phased risk-based assessment process that is iterative and that tailors site rehabilitation actions to site-specific conditions, the party or parties responsible for SRAs may submit to the Department for approval a proposal to establish applicable exposure factors and a risk management approach based upon land use at the site pursuant to the requirements set forth in Section 24-44(2)(k)(ii) and Section 24-44(2)(l)(ii).
(h)
Site rehabilitation actions shall neither be, nor reasonably be expected to be, a source of pollution, as herein defined, or cause, or reasonably be expected to cause, a nuisance as defined in Section 24-5, Section 24-27 or Section 24-28.
(i)
Emergency response actions may be performed without prior approval from the Director, or the Director's designee, provided that these actions do not cause any adverse effects upon human health, public safety or the environment. The party or parties responsible for SRAs and performing the emergency response actions shall notify the Director, or the Director's designee, within 24 hours of the commencement of any such emergency response actions.
(j)
Point of compliance, notification, source removal, and assessment procedures shall be as follows:
(i)
The sampling points to determine compliance with Section 24-44(2) shall be as set forth in Section 24-44.1 herein. However, contamination may exist beyond the property boundary while clean-up, including natural attenuation in conjunction with appropriate monitoring, is proceeding.
(ii)
When contamination exists beyond the property boundary of the site from which SRAs have been initiated the party or parties responsible for SRAs shall commence notification in accordance with the following:
1.
Laboratory analytical results, which comply with appropriate quality assurance protocols pursuant to Chapter 62-160, F.A.C., that document the off-site contamination, shall be submitted to the Department no later than ten (10) calendar days from the date that the laboratory analyses are completed. A site sketch shall be submitted along with the laboratory analytical data which indicates the locations where the samples were obtained that resulted in the confirmation of the contamination.
2.
The property owners, residents, and tenants of any property onto or into which the contamination extends shall be notified within sixty (60) calendar days of the approval of the site assessment report. Notification shall include, but not be limited to, the following type of information: the type of contaminant and site remedy selected, a description of the location of the subject site, the name and address of the party or parties responsible for SRAs, and the name of a Department contact. Persons receiving notice shall have thirty (30) calendar days upon receipt of the notice to comment on the assessment and the site remedy selected. Nothing herein shall preclude any persons from initiating a civil action as a result of said contamination.
(iii)
Prior to site closure as set forth in Section 24-44(2)(k), source removal of free product and soil saturated with contaminants or free product is required, unless demonstrated through a feasibility study approved by the Director, or the Director's designee, that the source removal is neither cost effective nor technically feasible. Source removal of free product from a new discharge shall be initiated as soon as possible but, in any event, no later than seven (7) calendar days after the discovery of free product. Source removal of free product from a previous discharge shall be initiated in accordance with the written orders of the Director, or the Director's designee, or the timeframes set forth in a source removal plan approved by the Director or the Director's designee.
Source removal of contaminated soils and saturated soils by excavation may be implemented at any time upon prior written notification by the party or parties responsible for SRAs to the Director or the Director's designee. Such notification shall be submitted to the Department at least three (3) calendar days prior to performing the source removal by excavation. Excavated soils shall be disposed of in accordance with 40 CFR 261, 40 CFR 761, Chapter 62-701, F.A.C., Chapter 62-713, F.A.C., and any other applicable federal, state and local regulations. A source removal report shall be submitted to the Department within sixty (60) calendar days of completion of the source removal. The source removal report shall describe all activities performed during the source removal including all analytical results as well as all disposal manifests.
When excavated soil is temporarily stored or stockpiled on site, the soil shall be secured in a manner which prevents human exposure to contaminated soil and prevents soil exposure to conditions which may facilitate the spread of contamination. Any excavation shall be secured to prevent accidental or intentional entry by the public and shall comply with applicable federal, state and local regulations. Contaminated soils may be stored on site for ninety (90) calendar days, unless otherwise ordered by the Director or the Director's designee. Prior to the expiration of the ninety (90) calendar day period, the soils shall be disposed of in accordance with this section.
(iv)
The site assessment report shall include, but not be limited to: an investigation of the source(s) of contamination; an identification of the types of contaminants present; a determination of the extent and degree of contamination in all media which are impacted; a determination of the physical and environmental conditions and characteristics of the site and the underlying aquifer(s), if applicable; an identification of potential human and environmental receptors; and an evaluation of the current exposure and potential risk of exposure to those identified receptors. Groundwater sampling shall be performed less than two hundred seventy (270) calendar days before the submittal of the site assessment report.
The summary and conclusions of the approved site assessment report shall propose one of the following: no further action, no further action with conditions, monitoring only, risk assessment, or a remedial action plan.
(k)
Site closure, in the form of a no further action or a no further action with conditions, shall be approved by the Director, or the Director's designee, when the CTLs or alternative CTLs established pursuant to Section 24-44(2)(f)(iii) and the requirements set forth in this section have been achieved.
(i)
A no further action proposal shall be approved by the Director, or the Director's designee, if such proposal demonstrates that human health, public safety and the environment are protected and the following criteria are met:
1.
Concentrations of contaminants detected in soil shall not exceed the lower of the direct exposure residential soil CTLs or the applicable leachability-based soil CTLs set forth in Section 24-44(2)(f)(v)(ii).
The applicable leachability-based soil CTLs shall be the groundwater leachability-based CTLs. If surface waters are, or are reasonably expected to be, affected by contaminated groundwater, as demonstrated using monitoring well data, groundwater flow rate and direction, or fate and transport modeling, then the applicable leachability-based soil CTLs shall be the lower of the groundwater or the applicable freshwater or marine surface water leachability-based CTLs.
Notwithstanding the foregoing provisions of Section 24-44(2)(k)(i)1, alternative residential direct exposure and leachability-based CTLs may be proposed in accordance with the procedures set forth in Section 24-44(2)(f)(iii)3. and Section 24-44(2)(f)(iii)4.
2.
Concentrations of contaminants detected in groundwater shall not exceed the groundwater CTLs set forth in Section 24-44(2)(f)(v)1.
If surface waters are, or are reasonably expected to be, affected by contaminated groundwater, as demonstrated using monitoring well data, groundwater flow rate and direction, or fate and transport modeling, then the groundwater CTLs shall be the lower of the groundwater CTLs or the applicable freshwater or marine surface water CTLs set forth in Section 24-44(2)(f)(v)1.
3.
Concentrations of contaminants detected in surface water shall not exceed the applicable freshwater or marine surface water CTLs set forth in Section 24-44(2)(f)(v)1.
Nothing herein shall supersede the rules governing Outstanding Florida Waters, aquatic preserves, areas of critical state concern and any other rules adopted pursuant to Section 403.061(34), Florida Statutes.
4.
It is demonstrated that contaminants in sediments are not detected in concentrations, quantities, properties, levels or accumulations which are, or are reasonably expected to be, injurious to human, plant, animal, fish and other aquatic life, or property. This demonstration may be based, as applicable, on the Threshold Effects Levels published in the FDEP's guideline "Approach to the Assessment of Sediment Quality in Florida Coastal Waters" (dated November 1994), site specific bioassays, a site-specific risk assessment developed in accordance with Section 24-44(2)(1)(ii), or a combination thereof.
5.
If more than one contaminant is present or contamination is present in more than one (1) medium, the human health-based CTLs shall be adjusted to achieve the following: for non-carcinogenic compounds affecting the same organ(s), the hazard index (sum of the hazard quotients) shall be one (1) or less; and for carcinogens, the cumulative lifetime excess cancer risk level (sum of the lifetime excess cancer risk levels for each carcinogenic contaminant) shall be 1.0E-06 or less.
(ii)
A no further action with conditions proposal shall be approved by the Director, or the Director's designee, provided the following: the property owner of the location elects to implement institutional and, if applicable, engineering controls; it is demonstrated, using site-specific data, modeling results, risk assessment studies, risk reduction techniques or a combination thereof, that human health, public safety and the environment are afforded protection equivalent to that provided in Section 24-44(2)(f)(i) and Section 24-44(2)(f)(ii); and the following criteria are met:
1.
For contaminants detected in soil, a proposal for alternative soil CTLs shall be submitted to the Department and shall achieve one of the following or a combination of the following:
a.
Concentrations of contaminants detected in soil shall not exceed the lower of the industrial direct exposure soil CTLs set forth in Section 24-44(2)(f)(v)2. or the applicable leachability-based soil CTLs, set forth in Section 24-44(2)(f).
The applicable leachability-based soil CTLs shall be the groundwater leachability-based CTLs or alternative groundwater leachability-based CTLs derived in accordance with Section 24-44(2)(k)(ii)1c and Section 24-44(2)(k)(ii)2. If surface waters are, or are reasonably expected to be, affected by contaminated groundwater, as demonstrated using monitoring well data, groundwater flow rate and direction, or fate and transport modeling, then the applicable leachability-based soil CTLs shall be the lower of the groundwater or the applicable freshwater or marine surface water leachability-based CTLs.
If a marine surface water is, or is reasonably expected to be, affected by contaminated groundwater, and no other property or fresh surface water bodies are located between the source property boundary and the marine surface water body and the groundwater on-site is not utilized, then the applicable leachability-based soil CTLs shall be the marine surface water leachability-based soil CTLs.
Notwithstanding the foregoing provisions of Section 24-44(2)(k)(ii)1a, alternative industrial direct exposure and leachability-based CTLs may be proposed in accordance with the procedures set forth in Section 24-44(2)(f)(iii)3 and Section 24-44(2)(f)(iii)4. In addition, the applicable leachability-based soil CTLs may be exceeded if it is demonstrated using groundwater monitoring data supported, if required, by site-specific modeling, that contaminants will not leach into groundwater at concentrations which exceed the applicable groundwater CTLs. The groundwater monitoring data shall be compiled for a minimum period of one (1) year and shall include four (4) quarterly sampling events.
b.
Concentrations of contaminants may exceed the soil CTLs if an engineering control, approved by the Director, or the Director's designee, in conjunction with the institutional control, is utilized to eliminate or control contaminant exposure and migration such that human health, public safety and the environment are afforded protection equivalent to that provided in Section 24-44(2)(f)(i) and Section 24-44(2)(f)(ii).
c.
Concentrations of contaminants detected in soil shall not exceed the alternative soil CTLs derived in accordance with Section 24-44(2)(f)(iii) and Section 24-44(2)(1)(ii).
2.
For contamination detected in groundwater, a proposal for alternative groundwater CTLs shall be submitted to the Department and shall provide the following:
a.
A complete evaluation of the current and projected use of the affected groundwater and documentation that the following conditions have been met:
(1)
Source removal is completed as set forth in Section 24-44(2)(j)(iii).
(2)
Groundwater contamination is not migrating away from a localized source.
(3)
Groundwater concentrations at the property boundary, as determined by groundwater monitoring data supported, if required, by site-specific modeling, do not, and are not reasonably expected to, exceed the groundwater CTLs set forth in Section 24-44(2)(f)(v)1. The groundwater monitoring data shall be compiled for a minimum period of one (1) year and shall include four (4) quarterly sampling events.
If surface waters are, or are reasonably expected to be, affected by contaminated groundwater, as demonstrated using monitoring well data, groundwater flow rate and direction, or fate and transport modeling, then the groundwater CTLs shall be the lower of the groundwater CTLs or the applicable freshwater or marine surface water CTLs set forth in Section 24-44(2)(f)(v)1.
If a marine surface water is, or is reasonably expected to be, affected by contaminated groundwater, and no other property or fresh surface water bodies are located between the source property boundary and the marine surface water body and the groundwater on-site is not utilized, then the groundwater CTLs shall be the marine surface water CTLs.
b.
If there is a receptor which may potentially be exposed to on-site groundwater and such exposure has not been eliminated by the implementation of institutional and, if applicable, engineering controls, then concentrations of contaminants detected in groundwater shall not exceed the alternative groundwater CTLs derived in accordance with Section 24-44(2)(f)(iii) and Section 24-44 (2)(1)(ii).
3.
Concentrations of contaminants detected in surface water shall not exceed the applicable freshwater or marine surface water CTLs set forth in Section 24-44(2)(f)(v)1.
Nothing herein shall supersede the rules governing Outstanding Florida Waters, aquatic preserves, areas of critical state concern and any other rules adopted pursuant to Section 403.061(34), Florida Statutes.
4.
It is demonstrated that contaminants in sediments are not detected in concentrations, quantities, proportions, levels or accumulations which are, or are reasonably expected to be, injurious to human, plant, animal, fish and other aquatic life, or property. This demonstration may be based, as applicable, on the Threshold Effects Levels published in the FDEP's guideline "Approach to the Assessment of Sediment Quality in Florida Coastal Waters" (November 1994), site specific bioassays, a site-specific risk assessment developed in accordance with Section 24-44(2)(l)(ii), or a combination thereof.
5.
If more than one (1) contaminant is present or contamination is present in more than one (1) media, the human health-based CTLs or alternative human health-based CTLs shall be adjusted to achieve the following: for non-carcinogenic compounds affecting the same organ(s), the hazard index (sum of the hazard quotients) shall be one (1) or less; and for carcinogens, the cumulative lifetime excess cancer risk level (sum of the lifetime excess cancer risk levels for each carcinogenic contaminant) shall be 1.0E-06 or less.
6.
The property owner of the location at which site rehabilitation actions are being conducted elects to implement an institutional and, if applicable, engineering control to eliminate or control exposure of human and environmental receptors to contaminants. When an engineering control is used in conjunction with institutional controls, an engineering control plan shall be submitted to the Department. The engineering control plan shall provide details of the design and construction of the engineering control and shall demonstrate that the engineering control is effective, reliable and capable of being monitored and maintained.
The no further action with conditions proposal shall include a copy of the proposed institutional control, in a form prescribed by the Director, or the Director's designee, and approved by the Board of County Commissioners, with site-specific closure conditions. Upon written approval by the Director, or the Director's designee, of the institutional control and, if applicable, the engineering control plan, the institutional control shall be recorded in the public records of Miami-Dade County. A copy of the recorded instrument shall be submitted to the Department and the engineering control, if applicable, shall be implemented prior to approval of the no further action with conditions proposal.
Upon demonstration to the satisfaction of the Director, or the Director's designee, by the party or parties responsible for SRAs that institutional and, if applicable, engineering controls are no longer required because the conditions set forth in Section 24-44(2)(k)(i) have been achieved, the Director, or the Director's designee, shall release the institutional control.
7.
An operating permit in accordance with Section 24-18 shall be required for all sites for which site rehabilitation actions have been completed in accordance with the provisions set forth in Section 24-44(2)(k)(ii). The Director, or the Director's designee, shall approve, deny, or approve with conditions, restrictions or limitations any application for an operating permit.
(l)
For sites which do not qualify for site closure in accordance with Section 24-44(2)(k), one (1) of the following, or a combination of the following, shall be submitted for approval by the Director, or the Director's designee, to achieve site closure pursuant to Section 24-44(2)(k): a monitoring only plan, a risk assessment report, or a remedial action plan.
(i)
The monitoring only plan:
1.
The monitoring only plan for natural attenuation shall include, but shall not be limited to, an evaluation of the contaminant plume history, site conditions and aquifer chemical characteristics to demonstrate that the applicable CTLs will be attained in accordance with the approval by the Director, or the Director's designee, and that monitoring only is the most cost-effective remedial approach. The monitoring period shall be a minimum of one (1) year, unless two (2) consecutive quarterly samplings have indicated that applicable CTLs have been met. The monitoring only plan shall also demonstrate that human health, public safety, and the environment will be protected. Upon completion of the approved monitoring, a proposal for a no further action, a no further action with conditions, an extension of the monitoring only plan, risk assessment, or a remedial action plan, in accordance with the requirements herein, shall be submitted to the Department.
2.
The monitoring only plan to verify that compliance with the approved remedial action as set forth in Section 24-44(2)(l)(iii) has been achieved shall be for a minimum of a one (1) year period and shall include four (4) quarterly sampling events. However, if contamination was only present in the unsaturated zone during the site assessment and remediation tasks, only one groundwater sampling event approved by the Director, or the Director's designee, shall be required. Upon completion of the approved monitoring, a proposal for a no further action, a no further action with conditions, an extension of the monitoring only plan, risk assessment, or a remedial action plan modification, in accordance with the requirements herein, shall be submitted to the Department for approval.
(ii)
The risk assessment shall include, but shall not be limited to, a human and environmental exposure assessment, toxicity assessment, cumulative risk characterization, and supporting documentation for the development of alternative CTLs. Alternative health-based CTLs shall be calculated using the risk equations set forth in the DERM Technical Report: "Development of Clean-up Target Levels (CTLs) for Chapter 24 of the Code of Miami-Dade County, Florida" (dated September, 2005), and site-specific exposure scenarios and input parameters. Upon approval of the risk assessment, a proposal for a no further action, no further action with conditions, monitoring only plan for natural attenuation or remedial action, in accordance with the requirements herein, shall be submitted to the Department.
(iii)
The remedial action plan shall include, but not be limited to, all supporting documentation for the remedial technique proposed to achieve CTLs or alternative CTLs, or to qualify for natural attenuation in all contaminated media. Groundwater sampling shall be performed less than two hundred seventy (270) calendar days before the submittal of the remedial action plan to the Department. Detailed technical documentation shall be provided for all elements of the proposed remedial process. Pilot testing may be required to support the design. A monitoring schedule shall be included to evaluate the performance of the clean-up. Within one hundred twenty (120) calendar days after the approval of the remedial action plan, the approved remedial action plan shall be implemented and record drawings of the operating remedial system shall be submitted. Upon achieving the CTLs or alternative CTLs, or qualifying for natural attenuation in all contaminated media, a monitoring only plan, prepared in accordance with the requirements set forth in Section 24-44(2)(l)(i), shall be submitted to the Department.
If implementation of the approved remedial action plan does not achieve the CTLs or alternative CTLs, or does not qualify for natural attenuation in all contaminated media a proposal for a monitoring only plan for natural attenuation, a risk assessment, or a remedial action plan modification, in accordance with the requirements herein, shall be submitted to the Department.
(m)
All sampling and analyses shall be performed in accordance with Chapter 62-160, F.A.C., Quality Assurance. Reports submitted to the Department which contain analytical data shall include, at a minimum, the following: original laboratory reports which include all information required in Chapter 62-160.670, F.A.C.; copies of the completed chain of custody records; copies of the completed water sampling log forms; and results from screening tests or on-site analyses.
(Ord. No. 04-214, §§ 1, 5, 12-2-04; Ord. No. 06-34, §§ 1—8, 3-7-06; Ord. No. 08-55, § 2, 5-6-08)